335452

三甲基硅烷基乙炔锂 溶液

0.5 M in THF

• 同義詞: 三甲基硅基乙炔锂
• 線性公式: (CH₃)₃SiC≡CLi
• CAS號碼: 54655-07-1
• 分子量：: 104.15
• Beilstein: 3587411
• MDL號碼: MFCD00075059
• 分類程式碼代碼: 12352103
• PubChem物質ID: 24860321
• NACRES: NA.22

屬性

• 形狀: liquid
• 品質等級: 100
• 濃度: 0.5 M in THF
• 密度: 0.88 g/mL at 25 °C
• SMILES 字串: [Li]C#C[Si](C)(C)C
• InChI: 1S/C5H9Si.Li/c1-5-6(2,3)4;/h2-4H3;
• InChI 密鑰: ZVXXEONXFWSCIZ-UHFFFAOYSA-N

描述

應用

Lithium (trimethylsilyl)acetylide can be used as a reagent:

• In the transmetalation and nucleophilic displacement reactions.
• To prepare propargylic alcohol derivatives by reacting with aldehydes and ketones.
• To synthesize α,βynones by treating with Weinreb amide or with isoxazolidide.
• Along with Grignard reagent to convert γ- and δ-thiolactams to thioiminium salts, which are employed as key intermediates to produce disubstituted pyrrolidines.

Reacts with halotriazines to produce conductive, anisotropic carbon-nitrogen materials.

包裝

The 25 mL Sure/Seal^™ bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.

法律資訊

Sure/Seal is a trademark of Sigma-Aldrich Co. LLC

安全資訊

• 象形圖: GHS02,GHS08,GHS05,GHS07
• 訊號詞: Danger
• 危險聲明: H225,H302,H314,H335,H336,H351
• 防範說明: P210 - P280 - P301 + P312 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• 危險分類: Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3
• 標靶器官: Respiratory system
• 安全危害: EUH019
• 儲存類別代碼: 3 - Flammable liquids
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: -9.4 °F - closed cup
• 閃點（°C）: -23 °C - closed cup
• 個人防護裝備: Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter