推薦產品
形狀
liquid
品質等級
反應適用性
reaction type: Grignard Reaction
濃度
0.5 M in THF
密度
0.921 g/mL at 25 °C
儲存溫度
2-8°C
SMILES 字串
Cl[Mg]C#C
InChI
1S/C2H.ClH.Mg/c1-2;;/h1H;1H;/q;;+1/p-1
InChI 密鑰
YEWNLGTVYUADOR-UHFFFAOYSA-M
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應用
Ethynylmagnesium chloride solution can be used:
- To synthesize 1-ethynyldeoxyribose derivatives which can further undergo Sonogashira coupling with various aryl, heteroaryl, and metallocenyl derivatives.
- In one of the key synthetic steps of substituted naphthostyrils.
- In the preparation of propargylic ester precursor for the synthesis of 1,3-dienylphosphonates.
訊號詞
Danger
危險分類
Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3
標靶器官
Central nervous system, Respiratory system
安全危害
儲存類別代碼
4.3 - Hazardous materials which set free flammable gases upon contact with water
水污染物質分類（WGK）
WGK 3
閃點（°F）
-16.6 °F - closed cup
閃點（°C）
-27 °C - closed cup
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A novel and convenient method for the synthesis of substituted naphthostyrils
Liu J, et al.
Tetrahedron Letters, 44(12), 2545-2548 (2003)
Sonogashira reactions of α-and β-1-ethynyl-2-deoxyribosides: synthesis of acetylene-extended C-nucleosides
Bobula T, et al.
Tetrahedron, 66(2), 530-536 (2010)
New and efficient synthesis of 1, 3-dienylphosphonates by Palladium-catalyzed substitution of propargylic esters to diethyl phosphite
Liu X, et al.
Synthetic Communications, 43(19), 2622-2626 (2013)
文章
Reagents for C–C Bond Formation
We carry a large variety of electrophiles and nucleophiles that are widely used in C–C bond-forming reactions. This group of products contains many organometallic reagents as well as commonly-used alkylating and acylating reagents.
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