跳轉至內容
Merck
全部照片(2)

文件

327638

Sigma-Aldrich

溴代五羰基铼(I)

98%

同義詞:

五羰基溴铼(I), 溴代五羰基铼

登入查看組織和合約定價


About This Item

線性公式:
Re(CO)5Br
CAS號碼:
分子量::
406.16
EC號碼:
MDL號碼:
分類程式碼代碼:
12161600
PubChem物質ID:
NACRES:
NA.22

化驗

98%

反應適用性

core: rhenium
reagent type: catalyst

SMILES 字串

Br[Re].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+]

InChI

1S/5CO.BrH.Re/c5*1-2;;/h;;;;;1H;/q;;;;;;+1/p-1

InChI 密鑰

NWJBOTGGBYFKEJ-UHFFFAOYSA-M

應用

用于研究三羰基环铼和二亚胺配体形成的 π-缺电子络合物,也可用于制备 [3]-二茂铁吩络合物。
用于研究三羰基环铼和二亚胺配体形成的 π-缺电子络合物。
铼-多吡啶络合物的原料,这种络合物在催化和太阳能转化中具有应用前景。

象形圖

Skull and crossbones

訊號詞

Danger

危險分類

Acute Tox. 3 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges


分析證明 (COA)

輸入產品批次/批號來搜索 分析證明 (COA)。在產品’s標籤上找到批次和批號,寫有 ‘Lot’或‘Batch’.。

已經擁有該產品?

您可以在文件庫中找到最近購買的產品相關文件。

存取文件庫

Ruimao Hua et al.
The Journal of organic chemistry, 69(17), 5782-5784 (2004-08-17)
The addition of carboxylic acids to terminal alkynes is efficiently catalyzed by the early transition-metal complex Re(CO)5Br in toluene or n-heptane at 110 degrees C in an air atmosphere, affording the anti-Markovnikov adducts in good yields with high selectivity. In
Jia-Li Jiang et al.
The Journal of organic chemistry, 70(1), 381-383 (2004-12-31)
In the presence of a catalytic amount of Re(CO)(5)Br, the coupling of epoxides with supercritical CO(2) without an organic solvent at 110 degrees C has afforded cyclic carbonates in good to excellent yields.
Nishiyama, Y.; Kakushou, F. et al.
Bulletin of the Chemical Society of Japan, 73, 2779-2779 (2000)
Tomás F Beltrán et al.
Dalton transactions (Cambridge, England : 2003), 46(28), 9036-9048 (2017-07-01)
The superbulky N-heterocyclic carbenes (NHCs) 2,6-bis(diphenylmethyl)-4-methylimidazol-2-ylidene (IDip*Me) and its 4-methoxy analogue (IDip*OMe) reacted instantaneously with carbon disulfide to afford the corresponding imidazolium-2-dithiocarboxylate zwitterions in high yields. These new dithiolate ligands were fully characterized and their coordination chemistry toward common Re(i)
Inorganic Chemistry, 29, 253-253 (1990)

我們的科學家團隊在所有研究領域都有豐富的經驗,包括生命科學、材料科學、化學合成、色譜、分析等.

聯絡技術服務