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Merck
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文件

206229

Sigma-Aldrich

氯化钌 (III) 水合物

ReagentPlus®

同義詞:

三氯化钌

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About This Item

線性公式:
RuCl3 · xH2O
CAS號碼:
14898-67-0
分子量：:
207.43 (anhydrous basis)
EC號碼:
233-167-5
MDL號碼:
MFCD00149844
分類程式碼代碼:
12352302
PubChem物質ID:
24852386
NACRES:
NA.23

品質等級

200

產品線

ReagentPlus®

形狀

powder and chunks

成份

Degree of hydration, ≤1
Ruthenium content, 40.00-49.00%

反應適用性

reagent type: catalyst
core: ruthenium

雜質

≤0.1% Insoluble matter (C=1%, 25% HCl)

SMILES 字串

O.Cl[Ru](Cl)Cl

InChI

1S/3ClH.H2O.Ru/h3*1H;1H2;/q;;;;+3/p-3

InChI 密鑰

BIXNGBXQRRXPLM-UHFFFAOYSA-K

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相關類別

一般說明

可溶型

應用

它被用于制备纳米颗粒钌-氢氧化铝氧化物催化剂，使芳甲基醇有效脱氢生成相应的醛。该产物可催化由伯芳香胺和三烯丙基胺合成2-乙基-3-甲基喹啉。使用 RhCl3 在二氧化钛纳米管上沉积制备的钌水合氧化物，可用作分子氧选择性氧化醇的催化体系。

法律資訊

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

訊號詞

Danger

危險聲明

H302 - H314 - H411

危險分類

Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Skin Corr. 1B

儲存類別代碼

8A - Combustible, corrosive hazardous materials

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

個人防護裝備

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

分析證明 (COA)

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TiO 2 nanotube-supported ruthenium (III) hydrated oxide: A highly active catalyst for selective oxidation of alcohols by oxygen.
Bavykin DV, et al.
J. Catal., 235(1), 10-17 (2005)
Won-Hee Kim et al.
Organic letters, 8(12), 2543-2545 (2006-06-02)
An efficient oxidant-free oxidation for a wide range of alcohols was achieved by a recyclable ruthenium catalyst. The catalyst was prepared from readily available reagents by a one-pot synthesis through nanoparticle generation and gelation. [structure: see text]
Cho, C.S. et al.
Tetrahedron Letters, 40, 1499-1499 (1999)
Yao Zhang et al.
European journal of medicinal chemistry, 86, 449-455 (2014-09-10)
Ruthenium-based anticancer complexes have become increasingly popular for study over the last two decades. Although ruthenium complexes are currently being investigated in clinical trials, there are still some difficulties with their delivery and associated side effects. Human serum albumin (HSA)-based
Huaiyi Huang et al.
Dalton transactions (Cambridge, England : 2003), 44(35), 15602-15610 (2015-08-08)
Ruthenium complexes have been considered as promising substitutes for cisplatin in cancer chemotherapy. However, novel ruthenium-based therapies are faced with some limitations, such as unimpressive cytotoxicity toward solid tumors. Herein, we designed and synthesized phenyl-substituted terpyridyl ruthenium(ii) complexes ([Ru(tpy)(bpy)Cl](+) (Ru1)
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