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重要文件

254142

Sigma-Aldrich

氯化铋 (III)

99.99% trace metals basis

同義詞:

三氯化铋, 三氯铋

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About This Item

經驗公式(希爾表示法):
BiCl3
CAS號碼:
分子量::
315.34
EC號碼:
MDL號碼:
分類程式碼代碼:
12352302
PubChem物質ID:
NACRES:
NA.23

等級

for analytical purposes

化驗

99.99% trace metals basis

形狀

solid

反應適用性

reagent type: catalyst
core: bismuth

雜質

≤150.0 ppm Trace Metal Analysis

bp

447 °C (lit.)

mp

230-232 °C (lit.)

SMILES 字串

Cl[Bi](Cl)Cl

InChI

1S/Bi.3ClH/h;3*1H/q+3;;;/p-3

InChI 密鑰

JHXKRIRFYBPWGE-UHFFFAOYSA-K

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一般說明

Bismuth(III) chloride is a Lewis acid catalyst and a common source of Bi3+ ions used in various organic transformations and synthesis of bismuth nanomaterials.

應用

Bismuth(III) chloride can be used:
  • As a precursor to prepare polyaniline and bismuth(III) telluride nanohybrids with high thermoelectric performance.
  • As a starting material to synthesize visible light absorbing double perovskite semiconductors, such as Cs2AgBiBr6 and Cs2AgBiCl6, eco-friendly alternative to the lead halide perovskites.
  • To form a protective layer on anode materials.
It can also be used as an efficient catalyst for green synthesis of:
  • Chalcones by Claisen–Schmidt reaction under solvent-free conditions.
  • One-pot three-component synthesis of Propargylamines.
  • Coumarins via ultrasound‐assisted Pechmann condensation of phenols with β‐ketoesters.

象形圖

Exclamation mark

訊號詞

Warning

危險聲明

危險分類

Eye Irrit. 2 - Skin Irrit. 2

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 2

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

dust mask type N95 (US), Eyeshields, Gloves


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分析證明 (COA)

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存取文件庫

Organic-inorganic nanohybrids as novel thermoelectric materials: hybrids of polyaniline and bismuth (III) telluride nanoparticles
Naoki Toshima, et al.
Journal of Electronic Materials, 40, 898-902 (2011)
Yunqing Zhu et al.
ACS nano, 8(5), 5022-5031 (2014-04-09)
Homopolymers have been considered as a nonideal building block for creating well-defined nanostructures due to their fuzzy boundary between hydrophobic and hydrophilic moieties. However, this unique fuzzy boundary may provide some opportunities for fabricating functional nanomaterials. Presented in this paper

文章

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