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重要文件

429414

Sigma-Aldrich

三氯化铟

anhydrous, powder, ≥99.999% trace metals basis

同義詞:

三氯化铟

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About This Item

線性公式:
InCl3
CAS號碼:
分子量::
221.18
EC號碼:
MDL號碼:
分類程式碼代碼:
12352302
PubChem物質ID:
NACRES:
NA.23

等級

anhydrous

品質等級

化驗

≥99.999% trace metals basis

形狀

powder

反應適用性

reagent type: catalyst
core: indium

雜質

<100 ppm H2O

密度

3.46 g/mL at 25 °C (lit.)

SMILES 字串

Cl[In](Cl)Cl

InChI

1S/3ClH.In/h3*1H;/q;;;+3/p-3

InChI 密鑰

PSCMQHVBLHHWTO-UHFFFAOYSA-K

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一般說明

InCl3 是一种高效的水稳定性路易斯酸催化剂,用于多种有机转化。它具有中等毒性,对大多数含氧和含氮官能团表现出高耐受性。由于其光电特性,它也被用于制备多种半导体材料。

應用

氯化铟(III)可以用作催化剂来合成:
  • 吲哚吲哚啉,通过吲哚的自加成作用。
  • 乙烯基吲哚,通过未官能化的吲哚和乙烯基叠氮化物。
  • 各种环加合物,通过烯烃缩醛与异戊二烯和环戊二烯反应生成。
  • N-甲苯磺酰胺,通过醛与对甲苯磺酰胺的缩合反应生成。

象形圖

Health hazardCorrosion

訊號詞

Danger

危險聲明

危險分類

Aquatic Chronic 3 - Eye Dam. 1 - Skin Corr. 1C - STOT RE 1 Inhalation

標靶器官

Lungs

儲存類別代碼

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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分析證明 (COA)

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Mechanisms of synthesis reaction of pure anhydrous indium(III) chloride
Wieslaw Gawel and Tomasz Kloc and Igor Mucha
Inorganica chimica acta, 495, 118991-118991 (2019)
Naveen Mulakayala et al.
Bioorganic & medicinal chemistry letters, 22(15), 5063-5066 (2012-07-04)
A convenient and practical methodology for the synthesis of 2-aryl quinazolin-4(3H)-ones by the condensation of o-aminobenzamides with aromatic aldehydes under mild conditions using catalytic InCl(3) with good yields and high selectivities. This method has been extended for the synthesis of
Masateru Ono et al.
Journal of natural products, 73(11), 1846-1852 (2010-10-14)
Treatment of the crude ether-insoluble resin glycoside (convolvulin) from seeds of Pharbitis nil (Pharbitis Semen), called pharbitin, with indium(III) chloride in methanol provided seven oligoglycosides of hydroxy fatty acid methyl esters partially acylated by 2-methyl-3-hydroxybutyric (nilic) and 2S-methylbutyric acids. Their
Enrique Font-Sanchis et al.
Dalton transactions (Cambridge, England : 2003), (14)(14), 2470-2473 (2009-03-26)
A simple method for the preparation of triorganoindium reagents under mild conditions based in indium-silicon exchange is described.
Christine Rangger et al.
International journal of nanomedicine, 7, 5889-5900 (2012-12-12)
Liposomes have been proposed to be a means of selectively targeting cancer sites for diagnostic and therapeutic applications. The focus of this work was the evaluation of radiolabeled PEGylated liposomes derivatized with varying amounts of a cyclic arginyl-glycyl-aspartic acid (RGD)

文章

Colloidal quantum dots (CQDs) are semiconducting crystals of only a few nanometers (ca. 2–12 nm) coated with ligand/surfactant molecules to help prevent agglomeration.

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