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Key Documents

205338

Sigma-Aldrich

四氯化碲

99%

同義詞:

Tellurium chloride, Tellurium(IV) chloride, Tetrachlorotellurium

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About This Item

線性公式:
TeCl4
CAS號碼:
分子量::
269.41
EC號碼:
MDL號碼:
分類程式碼代碼:
12352302
PubChem物質ID:
NACRES:
NA.23

化驗

99%

形狀

powder, crystals or chunks

bp

380 °C (lit.)

mp

224 °C (lit.)

密度

3.26 g/mL at 25 °C (lit.)

SMILES 字串

Cl[Te](Cl)(Cl)Cl

InChI

1S/Cl4Te/c1-5(2,3)4

InChI 密鑰

SWLJJEFSPJCUBD-UHFFFAOYSA-N

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一般說明

基材原子序数:52 碲

應用

  • 有机碲化合物的高效区域选择性合成:探索了四氯化碲与1-烯烃的反应,重点介绍了其在有机合成中的用途(VA Potapov et al., 2017)。
  • 环化反应:TeCl4 可用作双亲电子环化(double-electrophilic cyclization)反应的双亲电子试剂,显示了其在有机转化中的多功能性 (N Korol, M Slivka, 2018)。
  • 四氯化碲的区域和立体选择性加成:研究了甲基炔丙基醚中TeCl4 的加成,强调了加成过程的立体化学结构(MV Musalova et al., 2017)。

象形圖

Corrosion

訊號詞

Danger

危險聲明

危險分類

Skin Corr. 1B

儲存類別代碼

8A - Combustible corrosive hazardous materials

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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Maria V Musalova et al.
Molecules (Basel, Switzerland), 17(5), 5770-5779 (2012-05-17)
The reaction of tellurium tetrachloride with acetylene proceeds in a stereospecific anti-addition manner to afford the novel products E-2-chlorovinyltellurium trichloride and E,E-bis(2-chlorovinyl)tellurium dichloride. Reaction conditions for the selective preparation of each of these products were found. The latter was obtained
Puneet Vij et al.
Environmental toxicology and pharmacology, 34(3), 768-782 (2012-10-17)
Diphenyl ditelluride (DPDT) and tellurium tetrachloride (TeCl(4)) were evaluated for toxicity in transformed (HT-29, Caco-2) and non-transformed colon cells (CCD-18Co). Significant decreases in viability were observed with DPDT exposure in HT-29 (62.5-1000 μM), Caco-2 (31.25-1000 μM) and CCD-18Co cells (500-1000
P Mareeswari et al.
Enzyme and microbial technology, 95, 225-229 (2016-11-22)
We report an efficient method to biosynthesize biocompatible cadmium telluride and cadmium sulphide quantum dots from the fungus Rhizopus stolonifer. The suspension of the quantum dots exhibited purple and greenish-blue luminescence respectively upon UV light illumination. Photoluminescence spectroscopy, X-ray diffraction
J F Van Vleet et al.
American journal of veterinary research, 43(11), 2000-2009 (1982-11-01)
Seventy newly hatched ducklings were fed a commercial ration with 500 mg of added Te (as tetrachloride)/kg of feed for up to 28 days. Ducklings were euthanatized at day 14, 21, and 28, the hearts were studied by gross, microscopic
Shalini Roy et al.
Food and chemical toxicology : an international journal published for the British Industrial Biological Research Association, 49(10), 2564-2574 (2011-07-12)
Tellurium tetrachloride (TeCl(4)) and diphenyl ditelluride (DPDT) cytotoxicity, was investigated in rat astrocytes. Concentrations of 0.24-250μM (24h) were tested for viability using MTT(3-[4,5-dimethylthiazol-2-yl]-2,5-diphenyl tetrazolium bromide) and trypan blue exclusion. MTT showed significant decreases at all concentrations tested for both compounds.

文章

High Purity Metalorganic Precursors for CPV Device Fabrication

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