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重要文件

196231

Sigma-Aldrich

4-苯基环己酮

≥98%

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About This Item

線性公式:
C6H5C6H9(=O)
CAS號碼:
分子量::
174.24
Beilstein:
2045904
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

品質等級

化驗

≥98%

形狀

solid

mp

73-77 °C (lit.)

官能基

ketone
phenyl

SMILES 字串

O=C1CCC(CC1)c2ccccc2

InChI

1S/C12H14O/c13-12-8-6-11(7-9-12)10-4-2-1-3-5-10/h1-5,11H,6-9H2

InChI 密鑰

YKAYMASDSHFOGI-UHFFFAOYSA-N

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一般說明

4-Phenylcyclohexanone undergoes Ruthenium-catalyzed reaction with tributylamine to yield 2-butyl-4-phenylcyclohexanone and 2,6-dibutyl-4-phenylcyclohexanone. Wittig reaction of 4-phenylcyclohexanone with (carbethoxymethylene)triphenylphosphorane under microwave irradiation has been investigated.

應用

4-Phenylcyclohexanone was used in the preparation of new cardo diamine monomer, 1,1-bis[4-(4-aminophenoxy)phenyl]-4-phenylcyclohexane bearing a 4-phenylcyclohexylidene unit.

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

212.0 °F - closed cup

閃點(°C)

100 °C - closed cup

個人防護裝備

Eyeshields, Gloves, type N95 (US)


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Synthesis and Characterization of New Cardo Polyamides and Polyimides bearing a 4-Phenylcyclohexylidene Unit.
Liaw D-J, et al.
Macromolecular Chemistry and Physics, 202(6), 807-813 (2001)
Ruthenium-Catalyzed Regioselective alpha-Alkylation of Ketones: The First Alkyl-Group Transfer from Trialkylamines to the alpha-C Atom of Ketones This work was supported by the Basic Research Program of the Korea Science and Engineering Foundation (2000-2-12200-001-3). C.S.C. gratefully acknowledges a Post-Doctoral Fellowship of Kyungpook National University (2000).
Chan Sik Cho et al.
Angewandte Chemie (International ed. in English), 40(5), 958-960 (2001-03-10)
Highly regioselective Wittig reactions of cyclic ketones with a stabilized phosphorus ylide under controlled microwave heating.
Wu J, et al.
Tetrahedron Letters, 45(22), 4401-4404 (2004)
Alejandro Gran-Scheuch et al.
Frontiers in microbiology, 9, 1609-1609 (2018-08-04)
Actinobacteria are an important source of commercial (bio)compounds for the biotechnological and pharmaceutical industry. They have also been successfully exploited in the search of novel biocatalysts. We set out to explore a recently identified actinomycete, Streptomyces leeuwenhoekii C34, isolated from

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