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Key Documents

171441

Sigma-Aldrich

三氟碘甲烷

99%

同義詞:

三氟甲基碘, 全氟甲基碘, 碘代三氟甲烷

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About This Item

經驗公式(希爾表示法):
CF3I
CAS號碼:
分子量::
195.91
Beilstein:
1732740
EC號碼:
MDL號碼:
分類程式碼代碼:
12142100
PubChem物質ID:
NACRES:
NA.22

化驗

99%

bp

−22.5 °C (lit.)

mp

<−78 °C (lit.)

SMILES 字串

FC(F)(F)I

InChI

1S/CF3I/c2-1(3,4)5

InChI 密鑰

VPAYJEUHKVESSD-UHFFFAOYSA-N

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應用

用于 α,ß-不饱和酮的铑催化 α-三氟甲基化反应的试剂。

包裝

以Sure/Pac 气瓶供货,并具有配备 1/4" NPTF出口外螺纹的青铜针阀。使用样品筒之前,确保关闭阀门,然后拆下密封出气阀的镀锌钢六角帽。

与以下装置兼容:

法律資訊

Aldrich is a registered trademark of Sigma-Aldrich Co. LLC
Sure/Pac is a trademark of Sigma-Aldrich Co. LLC

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軟管倒鉤

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訊號詞

Warning

危險聲明

危險分類

Muta. 2 - Ozone 1 - Press. Gas Compr. Gas

儲存類別代碼

2A - Gases

水污染物質分類(WGK)

WGK 1

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

Eyeshields, Gloves


分析證明 (COA)

輸入產品批次/批號來搜索 分析證明 (COA)。在產品’s標籤上找到批次和批號,寫有 ‘Lot’或‘Batch’.。

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D E Dodd et al.
Inhalation toxicology, 11(11), 1041-1055 (1999-11-24)
CF(3)I is being considered by the U.S. Air Force as a replacement for Halon 1301 for fire-extinguishing requirements in unoccupied spaces. The purpose of this study was to determine and evaluate the potential for CF(3)I to produce reproductive toxicity and
C Stefan Lehmann et al.
Faraday discussions, 153, 173-187 (2011-01-01)
The control of multichannel ionic fragmentation dynamics in CF3I is studied by femtosecond pulse shaping and velocity map photoelectron photoion coincidence imaging. When CF3I is photoexcited with femtosecond laser pulses around 540 nm there are two major ions observed in
G Hancock et al.
Physical chemistry chemical physics : PCCP, 9(18), 2234-2239 (2007-05-10)
Frequency modulated diode laser based absorption at 1.315 microm has been used to measure the Doppler lineshapes of the I((2)P(1/2)-(2)P(3/2)) transition in atomic iodine produced from the 266 nm photolysis of both CF(3)I and C(2)F(5)I. Wavelength resolved laser gain is
A Vinegar et al.
Inhalation toxicology, 12(8), 751-763 (2000-07-06)
Most proposed replacements for Halon 1301 as a fire suppressant are halogenated hydrocarbons. The acute toxic endpoint of concern for these agents is cardiac sensitization. An approach is described that links the cardiac endpoint as assessed in dogs to a
Natalia B Shustova et al.
Journal of the American Chemical Society, 128(49), 15793-15798 (2006-12-07)
Reaction of a mixture of insoluble higher fullerenes with CF3I at 500 degrees C produced a single abundant isomer of C74(CF3)12, C76(CF3)12, and C80(CF3)12, two abundant isomers of C78(CF3)12 and C82(CF3)12, and an indeterminant number of isomers of C84(CF3)12. Using

文章

In 2001, Professor William Dolbier, Jr., at the University of Florida reported1 an approach to nucleophilic trifluoromethylation based on the generation of a trifluoromethyl anion using CF3I in the presence of a powerful twoelectron reductant, tetrakis(dimethylamino)ethylene (TDAE)

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