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重要文件

14814

Sigma-Aldrich

氯化钯(II)

anhydrous, 59-60% palladium (Pd) basis

同義詞:

Dichloropalladium, Palladium dichloride, Palladous chloride

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About This Item

經驗公式(希爾表示法):
Cl2Pd
CAS號碼:
分子量::
177.33
EC號碼:
MDL號碼:
分類程式碼代碼:
12161600
PubChem物質ID:
NACRES:
NA.22

品質等級

形狀

powder

反應適用性

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst

濃度

59-60% Pd

mp

678-680 °C (lit.)

密度

4 g/mL at 25 °C (lit.)

SMILES 字串

Cl[Pd]Cl

InChI

1S/2ClH.Pd/h2*1H;/q;;+2/p-2

InChI 密鑰

PIBWKRNGBLPSSY-UHFFFAOYSA-L

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應用

钯催化交叉偶联反应的应用指南

用于合成含半导体金属的聚合物,其中聚吡咯骨架具有最小构象能并且几乎是平面的。
Palladium catalysts and precursor used as an oxidizing agent and as a source of Pd(0) complexes.

訊號詞

Danger

危險分類

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Met. Corr. 1 - Skin Sens. 1

儲存類別代碼

8B - Non-combustible corrosive hazardous materials

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges


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分析證明 (COA)

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Annesofie Faurschou et al.
Contact dermatitis, 64(4), 185-195 (2011-03-12)
Consumers are mainly exposed to palladium from jewellery and dental restorations. Palladium contact allergy is nearly always seen together with nickel allergy, as palladium and nickel tend to cross-react. We aimed to analyse the available palladium patch test data and
Qianying Xu et al.
Analytica chimica acta, 707(1-2), 114-120 (2011-10-27)
In pH 1.7-3.5 acid medium, palladium chloride could react with adenine (A) to form a ternary complex of [PdCl(2)·A], which would self-aggregate to form uniformly dispersed nanoparticles-[PdCl(2)·A](n) with an average size of 42 nm through the squeezing effect of aqueous
Gábor Kovács et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 18(18), 5612-5619 (2012-03-31)
First-principles molecular dynamics coupled with metadynamics have been used to gain a deeper insight into the reaction mechanism of the Wacker process by determining the nature of the active species. An explicit and dynamic representation of the aqueous solvent, which
Ingmar Bürstel et al.
The Journal of biological chemistry, 286(52), 44937-44944 (2011-11-04)
The O(2)-tolerant [NiFe] hydrogenases of Ralstonia eutropha are capable of H(2) conversion in the presence of ambient O(2). Oxygen represents not only a challenge for catalysis but also for the complex assembling process of the [NiFe] active site. Apart from
Agnieszka Krogul et al.
Dalton transactions (Cambridge, England : 2003), 41(2), 658-666 (2011-11-10)
Palladium(II) complexes attract great attention due to their remarkable catalytic and biological activity. In the present study X-ray characterization, UV-Vis and Time-Dependent Density Functional Theory (TD-DFT) calculations for six PdCl(2)(XPy)(2) complexes (where: Py = pyridine; X = H, CH(3) or

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