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Key Documents

130621

Sigma-Aldrich

戊二腈

99%

同義詞:

1,3-二氰基丙烷

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About This Item

線性公式:
NC(CH2)3CN
CAS號碼:
分子量::
94.11
Beilstein:
1738385
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

品質等級

化驗

99%

形狀

liquid

折射率

n20/D 1.434 (lit.)

bp

285-287 °C (lit.)

mp

−29 °C (lit.)

溶解度

H2O: soluble
alcohol: soluble
chloroform: soluble

密度

0.995 g/mL at 25 °C (lit.)

官能基

nitrile

SMILES 字串

N#CCCCC#N

InChI

1S/C5H6N2/c6-4-2-1-3-5-7/h1-3H2

InChI 密鑰

ZTOMUSMDRMJOTH-UHFFFAOYSA-N

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應用

Glutaronitrile (1,3-Dicyanopropane) was used in the preparation of dicarbonyl compounds.
Glutaronitrile can be used as:
  • An electrolyte additive in high energy/power Li-ion batteries.
  • A glutarate ligand source to prepare zinc glutarate (ZnGA) by reacting with zinc perchlorate hexahydrate.
  • A reactant to synthesize pentanedithioamide by reacting with Lawesson′s reagent in the presence of boron trifluoride etherate (BF3.OEt2).

象形圖

Skull and crossbones

訊號詞

Danger

危險聲明

危險分類

Acute Tox. 3 Oral

儲存類別代碼

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

水污染物質分類(WGK)

WGK 3

閃點(°F)

233.6 °F - closed cup

閃點(°C)

112 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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分析證明 (COA)

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γ-butyrolactone and glutaronitrile as 5 V electrolyte additive and its electrochemical performance for LiNi0. 5Mn1. 5O4
Xu Yun, et al.
Journal of alloys and compounds, 698, 207-214 (2017)
M Zachariah et al.
Physical chemistry chemical physics : PCCP, 17(24), 16053-16057 (2015-06-02)
We probe the ionic conduction and the molecular dynamics in a pure and lithium-salt doped dinitrile molecular plastic crystal. While the diffusion of the Li(+) ions is decoupled from the molecular reorientational dynamics, in the undoped plastic crystal the temperature
Xingyong Wang et al.
The Journal of organic chemistry, 78(11), 5273-5281 (2013-05-15)
A palladium-catalyzed addition of potassium aryltrifluoroborates to aliphatic nitriles has been developed, leading to a wide range of alkyl aryl ketones with moderate to excellent yields. Moreover, several dinitriles (e.g., malononitrile, glutaronitrile, and adiponitrile) were applicable to this process for
Francesco Endrizzi et al.
Dalton transactions (Cambridge, England : 2003), 44(31), 13835-13844 (2015-05-01)
The complex formation between a cyclic ligand glutarimidoxioxime (denoted as HL(III) in this paper) and UO2(2+) is studied by potentiometry and microcalorimetry. Glutarimidoxioxime (HL(III)), together with glutarimidedioxime (H2L(I)) and glutardiamidoxime (H2L(II)), belongs to a family of amidoxime derivatives with prospective
Andreas Hofmann et al.
International journal of molecular sciences, 16(9), 20258-20276 (2015-09-08)
In this study, promising electrolytes for use in Li-ion batteries are studied in terms of interacting and wetting polyethylene (PE) and particle-coated PE separators. The electrolytes are characterized according to their physicochemical properties, where the flow characteristics and the surface

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