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Key Documents

125415

Sigma-Aldrich

1,4-环己二烯

97%

同義詞:

1,4-二氢苯

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About This Item

經驗公式(希爾表示法):
C6H8
CAS號碼:
分子量::
80.13
Beilstein:
1900733
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

品質等級

化驗

97%

形狀

liquid

包含

~0.1% hydroquinone as stabilizer

雜質

3% benzene

折射率

n20/D 1.472 (lit.)

bp

88-89 °C (lit.)

密度

0.847 g/mL at 25 °C (lit.)

儲存溫度

2-8°C

SMILES 字串

C1C=CCC=C1

InChI

1S/C6H8/c1-2-4-6-5-3-1/h1-2,5-6H,3-4H2

InChI 密鑰

UVJHQYIOXKWHFD-UHFFFAOYSA-N

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一般說明

1,4-环己二烯是催化加氢反应的有效氢供体。它能迅速地用氢取代N-苄氧基氨基甲酸酯、苄酯、苄醚和苄胺的苄基。在钌 (II)-三苯基膦催化剂存在下在高温下形成苯

應用

以1,4-环己二烯 (1,4-CHD) 为研究对象,研究了1,4-CHD 在强激光脉冲照射下的重碎裂形成母离子的过程
用于电子转移介导的开环反应中形成的自由基中间体的还原

象形圖

FlameHealth hazard

訊號詞

Danger

危險分類

Carc. 1A - Flam. Liq. 2 - Muta. 1B - STOT RE 2

標靶器官

Blood

儲存類別代碼

3 - Flammable liquids

水污染物質分類(WGK)

WGK 3

閃點(°F)

19.4 °F - closed cup

閃點(°C)

-7 °C - closed cup


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Rapid removal of protecting groups from peptides by catalytic transfer hydrogenation with 1, 4-cyclohexadiene.
Felix AM,et al.
The Journal of Organic Chemistry, 43(21), 4194-4196 (1978)
A key factor in parent and fragment ion formation on irradiation with an intense femtosecond laser pulse.
Harada H, et al.
Chemical Physics Letters, 342(5), 563-570 (2001)
Organometallics, 25, 5456-5456 (2006)
Kazutada Ikeuchi et al.
Organic letters, 14(23), 6016-6019 (2012-11-15)
Asymmetric bromolactonization of prochiral cyclohexadiene derivatives with N-bromosuccimide proceeded in the presence of (DHQD)(2)PHAL as a chiral catalyst to afford the corresponding bromolactones with up to 93% ee. This reaction was also applicable to the kinetic resolution of a racemic
Yide Gao et al.
The journal of physical chemistry. A, 113(25), 6955-6963 (2009-06-06)
A quantitative understanding of the thermochemistry of cyclohexadienyl radical and 1,4-cyclohexadiene is beneficial for diverse areas of chemistry. Given the interest in these two species, it is surprising that more detailed thermodynamic data concerning the homolytic C-H bond enthalpies of

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