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Key Documents

220159

Sigma-Aldrich

2,3-二甲基-2-丁烯

≥99%

同義詞:

四甲基乙烯

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About This Item

線性公式:
(CH3)2C=C(CH3)2
CAS號碼:
分子量::
84.16
Beilstein:
1361357
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

蒸汽壓力

215 mmHg ( 37.7 °C)

品質等級

化驗

≥99%

形狀

liquid

自燃溫度

754 °F

折射率

n20/D 1.412 (lit.)

bp

73 °C (lit.)

mp

−75 °C (lit.)

密度

0.708 g/mL at 25 °C (lit.)

儲存溫度

2-8°C

SMILES 字串

C\C(C)=C(\C)C

InChI

1S/C6H12/c1-5(2)6(3)4/h1-4H3

InChI 密鑰

WGLLSSPDPJPLOR-UHFFFAOYSA-N

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一般說明

2,3-二甲基-2-丁烯在黑暗中臭氧分解产生羟基自由基 。用流动管接口式紫外光电子能谱仪研究了臭氧与 2,3-二甲基-2-丁烯 (DMB) 的反应 。在 0°C 和-15°C 下,DMB 与四氟硼酸硫代阳离子自由基形成加合物

應用

2,3-二甲基-2-丁烯作为底物参与了 2-羟基-1,4-萘醌的光诱导分子转化

象形圖

FlameHealth hazard

訊號詞

Danger

危險聲明

危險分類

Asp. Tox. 1 - Flam. Liq. 2

儲存類別代碼

3 - Flammable liquids

水污染物質分類(WGK)

WGK 3

閃點(°F)

17.6 °F - closed cup

閃點(°C)

-8 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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The Journal of Organic Chemistry, 58, 4614-4614 (1993)
Bing-Jun Zhao et al.
The Journal of organic chemistry, 71(10), 3737-3742 (2006-05-06)
Thianthrene cation radical tetrafluoroborate (Th*+ BF4-) has been found to add to 2,3-dimethyl-2-butene (DMB) at 0 degrees C and -15 degrees C. The adduct, 2,3-dimethyl-2,3-(5,10-thianthreniumdiyl)butane ditetrafluoroborate (12), was isolated at -15 degrees C, and its 1H NMR spectrum was recorded
Maryline Pflieger et al.
Environmental science & technology, 47(12), 6239-6246 (2013-05-15)
In order to investigate the heterogeneous oxidation kinetics of the herbicide terbuthylazine (TERB), a stable and reproducible generation system of "dark" hydroxyl radical in the gas phase was developed and optimized using a PTR-MS. TERB was adsorbed on silica particles
L R Pohl et al.
Biochemical and biophysical research communications, 117(2), 367-371 (1983-12-16)
Although indirect evidence has suggested that liver microsomal cytochrome P-450 can reductively dehalogenate several compounds to carbene metabolites, there has been no direct proof for the formation of these reactive species. We report in this paper that carbenes can be
R Tolando et al.
Xenobiotica; the fate of foreign compounds in biological systems, 26(4), 425-435 (1996-04-01)
1. During anaerobic reductive incubation of liver microsomes, from either the pyridine- or phenobarbital-treated rat, with 1,1-dichloro-1-fluoroethane (HCFC-141b) in the presence of a NADPH-regenerating system, a time- and dose-dependent formation of reactive metabolites was detected as indicated by a depletion

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