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Merck

M87509

Sigma-Aldrich

3-丁烯-2-酮

contains 0.3-1.0% hydroquinone as stabilizer, technical grade, 90%

别名:

丁烯酮, 甲基乙烯基酮

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About This Item

线性分子式:
CH2=CHCOCH3
CAS号:
分子量:
70.09
Beilstein:
506021
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

等級

technical grade

品質等級

蒸汽密度

1.3 (vs air)

蒸汽壓力

310 mmHg ( 55 °C)
71 mmHg ( 20 °C)

化驗

90%

形狀

liquid

包含

0.3-1.0% hydroquinone as stabilizer

expl. lim.

15.64 %

雜質

<7% water

折射率

n20/D 1.411 (lit.)

bp

81 °C (lit.)

溶解度

H2O: soluble

密度

0.864 g/mL at 25 °C (lit.)

儲存溫度

2-8°C

SMILES 字串

CC(=O)C=C

InChI

1S/C4H6O/c1-3-4(2)5/h3H,1H2,2H3

InChI 密鑰

FUSUHKVFWTUUBE-UHFFFAOYSA-N

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應用

3-Buten-2-one can undergo conjugate addition with methanol over the solid base catalysts to afford 4-methoxy-butan-2-one. It can also undergo coupling reaction with alkyltins and alkynes in the presence of a nickel complex to form stereo-defined conjugated enynes.

訊號詞

Danger

危險分類

Acute Tox. 1 Dermal - Acute Tox. 1 Inhalation - Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - Skin Sens. 1

儲存類別代碼

3 - Flammable liquids

水污染物質分類(WGK)

WGK 3

閃點(°F)

19.4 °F - closed cup

閃點(°C)

-7 °C - closed cup

個人防護裝備

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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分析证书(COA)

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Synthesis of stereodefined enynes by the nickel-catalyzed coupling reaction of alkynyltins, alkynes, and enones.
Ikeda SI
Journal of the American Chemical Society, 116(13), 5975-5976 (1994)
Conjugate addition of methanol to 3-buten-2-one over solid base catalysts.
Kabashima H, et al.
Applied Catalysis A: General, 214(1), 121-124 (2001)
Qing Zhong et al.
Toxicology and applied pharmacology, 241(1), 1-13 (2009-08-18)
Diabetic nephropathy is characterized by increased oxidative stress and mitochondrial dysfunction. In the present study, we prepared primary cultures of proximal tubular (PT) cells from diabetic rats 30 days after an ip injection of streptozotocin and compared their susceptibility to
Hyun Joo Lee et al.
Molecules (Basel, Switzerland), 17(6), 7523-7532 (2012-06-20)
The enantioselective conjugate addition reaction of 3-aryl-substituted oxindoles with methyl vinyl ketone promoted by binaphthyl-modified bifunctional organocatalysts was investigated. The corresponding Michael adducts, containing a quaternary center at the C3-position of the oxindoles, were generally obtained in high yields with
Quan Cai et al.
Organic letters, 14(12), 3040-3043 (2012-05-26)
A formal [4 + 2] cycloaddition of 2,3-disubstituted indoles with vinyl methyl ketone was realized in the presence of a catalytic amount of quinine-derived primary amine and pentafluorobenzoic acid. This method provides bridged-ring indoline scaffolds containing two quaternary carbon centers

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