A36603

烯丙基三苯基溴化膦

99%

• 别名: 2-Propenyltriphenylphosphonium bromide, NSC 110609, NSC 59815
• 线性分子式: H₂C=CHCH₂P(C₆H₅)₃Br
• CAS号: 1560-54-9
• 分子量: 383.26
• EC號碼: 216-332-6
• MDL號碼: MFCD00011808
• 分類程式碼代碼: 12352002
• PubChem物質ID: 24890798
• NACRES: NA.22

属性

• 化驗: 99%
• 形狀: powder
• 反應適用性: reaction type: C-C Bond Formation
• mp: 222-225 °C (lit.)
• SMILES 字串: [Br-].C=CC[P+](c1ccccc1)(c2ccccc2)c3ccccc3
• InChI: 1S/C21H20P.BrH/c1-2-18-22(19-12-6-3-7-13-19,20-14-8-4-9-15-20)21-16-10-5-11-17-21;/h2-17H,1,18H2;1H/q+1;/p-1
• InChI 密鑰: FWYKRJUVEOBFGH-UHFFFAOYSA-M

说明

應用

Reactant for:

• Preparation of a diol and carbamate chemistry library for common functional groups
• Regioselective synthesis of alkenes via semihydrogenation and semihydrogenation-oxidation of dienes
• Alkene addition of frustrated Lewis pairs
• Olefination of N-sulfonyl imines for stereoselective synthesis of vinyl arenes
• Wittig olefination of aldehydes for preparation of conjugated dienes
• Tandem Michael addition / ylide olefination reactions for the synthesis of highly functionalized cyclohexadienes

安全信息

• 儲存類別代碼: 11 - Combustible Solids
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: Not applicable
• 閃點（°C）: Not applicable
• 個人防護裝備: dust mask type N95 (US), Eyeshields, Gloves