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Merck

E50604

Sigma-Aldrich

乙基三苯基膦

99%

别名:

TEP

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About This Item

线性分子式:
[(C6H5)3P+C2H5]Br-
CAS号:
分子量:
371.25
Beilstein:
3599630
EC號碼:
MDL號碼:
分類程式碼代碼:
12352002
PubChem物質ID:
NACRES:
NA.22

化驗

99%

反應適用性

reaction type: C-C Bond Formation

mp

203-205 °C (lit.)

SMILES 字串

[Br-].CC[P+](c1ccccc1)(c2ccccc2)c3ccccc3

InChI

1S/C20H20P.BrH/c1-2-21(18-12-6-3-7-13-18,19-14-8-4-9-15-19)20-16-10-5-11-17-20;/h3-17H,2H2,1H3;1H/q+1;/p-1

InChI 密鑰

JHYNXXDQQHTCHJ-UHFFFAOYSA-M

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應用

用于合成以下物质的反应物:
  • L-半胱氨酸衍生的噻唑烷的 D-氨基酸
  • 通过 醛醇缩合反应和 Horner-Wadsworth-Emmons 烯化合成Leiodolide A
  • 通过非对映选择性分子内亚胺反应合成环烷二氢吲哚
  • 通过关键构件的结合来合成WXYZA的毒素的结构域

作为以下反应物:
  • 形成烷基二丙烯基噻吩单体的固态复分解缩聚
  • Mizoroki-Heck环化和级联Tsuji-Trost环化/内酯化环化反应,用于合成ABC环系统

象形圖

Skull and crossbonesCorrosion

訊號詞

Danger

危險聲明

危險分類

Acute Tox. 3 Oral - Aquatic Chronic 3 - Eye Dam. 1

儲存類別代碼

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

水污染物質分類(WGK)

WGK 2

閃點(°F)

401.0 °F

閃點(°C)

205 °C

個人防護裝備

dust mask type N95 (US), Eyeshields, Faceshields, Gloves


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