797693

2-Chloro-6-(trimethylsilyl)phenyl triflate

• 别名: Garg 3-chlorobenzyne precursor
• 经验公式（希尔记法）: C₁₀H₁₂ClF₃O₃SSi
• CAS号: 1449472-59-6
• 分子量: 332.80
• 分類程式碼代碼: 12352100
• PubChem物質ID: 329768621
• NACRES: NA.22

属性

• 形狀: liquid
• 官能基: chloro; fluoro; triflate
• 儲存溫度: 2-8°C
• SMILES 字串: ClC1=C(OS(=O)(C(F)(F)F)=O)C([Si](C)(C)C)=CC=C1
• InChI: 1S/C10H12ClF3O3SSi/c1-19(2,3)8-6-4-5-7(11)9(8)17-18(15,16)10(12,13)14/h4-6H,1-3H3
• InChI 密鑰: QFWUIGWOSVHZMC-UHFFFAOYSA-N

说明

應用

Chlorosilyltriflate has been shown to be a useful precursor for the generation of a chlorobenzyne intermediate. The chlorobenzyne intermediate can be generated in the presence of Cesium or Potassium Fluoride and can be trapped with various dipolariphiles.

其他說明

Synchronous Ar-F and Ar-Sn Bond Formation Through Fluorostannylation of Arynes

安全信息

• 象形圖: GHS07
• 訊號詞: Warning
• 危險聲明: H315,H319,H335
• 防範說明: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• 危險分類: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• 標靶器官: Respiratory system
• 儲存類別代碼: 10 - Combustible liquids
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: Not applicable
• 閃點（°C）: Not applicable