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Merck

903191

Sigma-Aldrich

Benzyl 4-oxo-5-(triethylsilyl)-3,4-dihydropyridine-1(2H)-carboxylate

别名:

Garg silyl triflate precursor

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About This Item

经验公式(希尔记法):
C19H27NO3Si
分子量:
345.51
分類程式碼代碼:
12352005

形狀

liquid

折射率

n/D 1.548

密度

1.079 g/mL

儲存溫度

−20°C

應用

Benzyl 4-oxo-5-(triethylsilyl)-3,4-dihydropyridine-1(2H)-carboxylate is a precursor to a Garg silyl triflate which upon exposure to fluoride generates a reactive azacyclic allene for cycloaddition reactions.

儲存類別代碼

10 - Combustible liquids

水污染物質分類(WGK)

WGK 3


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Joyann S Barber et al.
Nature chemistry, 10(9), 953-960 (2018-08-01)
For over a century, the structures and reactivities of strained organic compounds have captivated the chemical community. Whereas triple-bond-containing strained intermediates have been well studied, cyclic allenes have received far less attention. Additionally, studies of cyclic allenes that bear heteroatoms

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