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767840

Sigma-Aldrich

二氟甲烷亚磺酸锌

95%

别名:

双（（二氟甲基）亚磺酰基）氧）锌, Baran 二氟甲基化试剂, DFMS

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About This Item

经验公式（希尔记法）:
C2H2F4O4S2Zn
CAS号:
1355729-38-2
分子量:
295.55
MDL號碼:
MFCD23134675
分類程式碼代碼:
12352103
PubChem物質ID:
329767342
NACRES:
NA.22

品質等級

100

化驗

95%

形狀

solid

反應適用性

reaction type: C-C Bond Formation
reaction type: Fluorinations
reagent type: catalyst
reaction type: C-H Activation
reagent type: diversification reagent

儲存溫度

2-8°C

SMILES 字串

FC(F)S(=O)O[Zn]OS(=O)C(F)F

InChI

1S/2CH2F2O2S.Zn/c2*2-1(3)6(4)5;/h2*1H,(H,4,5);/q;;+2/p-2

InChI 密鑰

UGEYAPVLXKEKMP-UHFFFAOYSA-L

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一般說明

二氟甲烷亚磺酸锌是广泛用于将二氟甲基官能团结合到生物学上重要的结构基序上的一种试剂。它可用于二氟甲基化一些化合物，例如杂芳烃、硫醇、烯酮和 α、 β不饱和羧酸。
材料与最多 1 当量的氯化锌络合

應用

二氟甲烷亚磺酸锌 (DFMS) 是 Phil Baran 开发的亚磺酸锌工具箱的一部分，用于杂环的简单快速多样化。†

杂环化合物的实用固有碳氢功能化

DFMS 是一种新型的有机底物自由基直接二氟甲基化试剂。这种温和、操作简单、化学选择性和可放大的二氟甲基化方法与一系列不同复杂程度的含氮杂芳烃底物以及选择的共轭 p-系统和硫醇类相容。†

一种新的直接二氟甲基化试剂

在 Phil S. Baran 教授的 教授和产品门户网站 了解更多信息。

聯結

本产品常见问题 。

象形圖

Exclamation mark
GHS07

訊號詞

Warning

危險聲明

H315,H319,H335

危險分類

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

11 - Combustible Solids

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

分析证书(COA)

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Jessy Aziz et al.
Organic & biomolecular chemistry, 12(48), 9743-9759 (2014-10-31)
Sulfinic acids and their salts have recently emerged as versatile coupling partners to efficiently access a wide variety of hetero- and carbocyclic compounds, under relatively mild conditions. Their growing importance is attributable to their dual capacity for acting as nucleophilic
Yuta Fujiwara et al.
Journal of the American Chemical Society, 134(3), 1494-1497 (2012-01-11)
Molecular scaffolds containing alkylfluorine substituents are desired in many areas of chemical research from materials to pharmaceuticals. Herein, we report the invention of a new reagent (Zn(SO(2)CF(2)H)(2), DFMS) for the innate difluoromethylation of organic substrates via a radical process. This
Fionn O'Hara et al.
Journal of the American Chemical Society, 135(32), 12122-12134 (2013-07-19)
Radical addition processes can be ideally suited for the direct functionalization of heteroaromatic bases, yet these processes are only sparsely used due to the perception of poor or unreliable control of regiochemistry. A systematic investigation of factors affecting the regiochemistry
Yuta Fujiwara et al.
Nature, 492(7427), 95-99 (2012-12-04)
Nitrogen-rich heterocyclic compounds have had a profound effect on human health because these chemical motifs are found in a large number of drugs used to combat a broad range of diseases and pathophysiological conditions. Advances in transition-metal-mediated cross-coupling have simplified

商品

Baran Diversinates™

The synthesis of heteroaromatic and aromatic compounds is at the heart of the chemical industry. The ever-growing demand for new chemical entities, coupled with dwindling resources and time constraints allotted to any given research project, a rapid way to diversify (hetero)aromatic scaffolds is needed.

Baran Diversinates™

The synthesis of heteroaromatic and aromatic compounds is at the heart of the chemical industry. The ever-growing demand for new chemical entities, coupled with dwindling resources and time constraints allotted to any given research project, a rapid way to diversify (hetero)aromatic scaffolds is needed.

我们的科学家团队拥有各种研究领域经验，包括生命科学、材料科学、化学合成、色谱、分析及许多其他领域.

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