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Sigma-Aldrich

三氟甲烷亚磺酸锌

别名:

TFMS, 双（（三氟甲基）亚磺酰基）氧）锌, 氟乙酸三氟甲基化试剂

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About This Item

经验公式（希尔记法）:
C2F6O4S2Zn
CAS号:
39971-65-8
分子量:
331.53
分類程式碼代碼:
12352103
NACRES:
NA.22

形狀

solid

品質等級

100

反應適用性

reaction type: C-C Bond Formation
reagent type: catalyst
reaction type: C-H Activation

mp

151-157 °C

儲存溫度

2-8°C

SMILES 字串

FC(F)(F)S(=O)O[Zn]OS(=O)C(F)(F)F

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應用

三氟甲烷亚磺酸锌 (TFMS) 是 Phil Baran 开发的亚磺酸锌工具箱的一部分，用于杂环的简单快速多样化。

杂环化合物的实用固有碳氢功能化

在 Phil S. Baran 教授的 教授和产品门户网站 了解更多信息。

聯結

本产品常见问题 。

象形圖

CorrosionExclamation mark
GHS05,GHS07

訊號詞

Danger

危險聲明

H315,H318,H335

危險分類

Eye Dam. 1 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

11 - Combustible Solids

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

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Fionn O'Hara et al.
Journal of the American Chemical Society, 135(32), 12122-12134 (2013-07-19)
Radical addition processes can be ideally suited for the direct functionalization of heteroaromatic bases, yet these processes are only sparsely used due to the perception of poor or unreliable control of regiochemistry. A systematic investigation of factors affecting the regiochemistry
Yuta Fujiwara et al.
Nature, 492(7427), 95-99 (2012-12-04)
Nitrogen-rich heterocyclic compounds have had a profound effect on human health because these chemical motifs are found in a large number of drugs used to combat a broad range of diseases and pathophysiological conditions. Advances in transition-metal-mediated cross-coupling have simplified

商品

Baran Diversinates™

The synthesis of heteroaromatic and aromatic compounds is at the heart of the chemical industry. The ever-growing demand for new chemical entities, coupled with dwindling resources and time constraints allotted to any given research project, a rapid way to diversify (hetero)aromatic scaffolds is needed.

Baran Diversinates™

The synthesis of heteroaromatic and aromatic compounds is at the heart of the chemical industry. The ever-growing demand for new chemical entities, coupled with dwindling resources and time constraints allotted to any given research project, a rapid way to diversify (hetero)aromatic scaffolds is needed.

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