735809

[2-（二叔丁基膦基甲基）-6-（二乙基氨基甲基）吡啶]羰基氯氢化钌（II）

• 别名: Milstein Catalyst Precursor, [2-(Di-tert-butylphosphinomethyl)-6-(diethylaminomethyl)pyridine]ruthenium(II) chlorocarbonyl hydride
• 经验公式（希尔记法）: C₂₀H₃₆ClN₂OPRu
• CAS号: 863971-62-4
• 分子量: 488.01
• MDL號碼: MFCD16038117
• 分類程式碼代碼: 12352300
• PubChem物質ID: 329765059
• NACRES: NA.22

属性

• 形狀: powder
• 反應適用性: core: ruthenium; reagent type: catalyst
• 環保替代產品特色: Catalysis; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• 環保替代類別: Aligned,
• SMILES 字串: Cl[RuH].[C-]#[O+].CCN(CC)Cc1cccc(CP(C(C)(C)C)C(C)(C)C)n1
• InChI: 1S/C19H35N2P.CO.ClH.Ru.H/c1-9-21(10-2)14-16-12-11-13-17(20-16)15-22(18(3,4)5)19(6,7)8;1-2;;;/h11-13H,9-10,14-15H2,1-8H3;;1H;;/q;;;+1;/p-1
• InChI 密鑰: RZCAJPSOQUIHSH-UHFFFAOYSA-M

说明

一般說明

May contain up to 10% acetone and/or THF.

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

應用

Precursor to active Ru catalyst for the dehydrogenative coupling of amines and alcohols to form amide bonds.

Precursor to active ruthenium catalyst for greener amide bond formation by dehydrogenative coupling of amines and alcohols.

Direct Synthesis of Amides from Alcohols and Amines with Liberation of H2

安全信息

• 象形圖: GHS08,GHS07
• 訊號詞: Warning
• 危險聲明: H319,H351
• 防範說明: P281 - P305 + P351 + P338
• 危險分類: Carc. 2 - Eye Irrit. 2
• 安全危害: EUH019
• 儲存類別代碼: 13 - Non Combustible Solids
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: Not applicable
• 閃點（°C）: Not applicable