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746339

Sigma-Aldrich

二氯三苯基膦[双（2-（乙硫基）乙基）胺]钌（II）

greener alternative

97%

别名:

Ru-SNS catalyst

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About This Item

经验公式（希尔记法）:
C26H34Cl2NPRuS2
CAS号:
1462397-86-9
分子量:
627.63
MDL號碼:
MFCD26960799
分類程式碼代碼:
12161600
PubChem物質ID:
329765759
NACRES:
NA.22

品質等級

100

化驗

97%

形狀

solid

反應適用性

core: ruthenium
reagent type: catalyst

環保替代產品特色

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

300-310 °C

環保替代類別

Aligned,

SMILES 字串

CCSCCN([H])CCSCC.Cl[Ru]Cl.P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3

InChI

1S/C18H15P.C8H19NS2.2ClH.Ru/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-3-10-7-5-9-6-8-11-4-2;;;/h1-15H;9H,3-8H2,1-2H3;2*1H;/q;;;;+2/p-2

InChI 密鑰

ZQGMNGJIEYHKBR-UHFFFAOYSA-L

相关类别

一般說明

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

應用

Catalyst for hydrogenation of esters to alcohols. Greener alternative to stoichiometric hydride reagents.

Replacing Phosphorus with Sulfur for the Efficient Hydrogenation of Esters
Catalyst for the hydrogenation of esters to alcohols.

其他說明

"The mer-SNS complexes form isomers in solution. This is due to the different arrangements of the SEt groups relative to the SNS ligand plane. Two of the isomers have eclipsed SEt groups (arranged on one side of the SNS plane), and the third isomer has staggered SEt groups (occupying the opposite sides of the SNS plane)."

法律資訊

This Product is licensed from GreenCentre Canada for non-commercial, research use only. Please contact GreenCentre Canada for information regarding commercial use of Product.

象形圖

Skull and crossbones
GHS06

訊號詞

Danger

危險聲明

H302 + H312,H331

危險分類

Acute Tox. 3 Inhalation - Acute Tox. 4 Dermal - Acute Tox. 4 Oral

儲存類別代碼

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

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分析证书(COA)

Lot/Batch Number
MKCK5335
MKBQ2000V

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Denis Spasyuk et al.
Angewandte Chemie (International ed. in English), 52(9), 2538-2542 (2013-01-29)
Catalyst tune-up: A readily available, air-stable amino-sulfide catalyst, [RuCl(2)(PPh(3)){HN(C(2)H(4)SEt)(2)}], has been developed. This complex displays outstanding efficiency for the hydrogenation of a broad range of substrates with C=X bonds (esters, ketones, imines), as well as for the acceptorless dehydrogenative coupling

商品

Ester Hydrogenation

Learn about Ester Hydrogenation from MilliporeSigma. The reduction of esters to alcohols is typically accomplished using metal hydrides. While effective, it comes at the cost of stoichiometric waste and complicated workup procedures.

Ester Hydrogenation

Learn about Ester Hydrogenation from MilliporeSigma. The reduction of esters to alcohols is typically accomplished using metal hydrides. While effective, it comes at the cost of stoichiometric waste and complicated workup procedures.

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