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Merck

746347

Sigma-Aldrich

Dichlorotriphenylphosphine[2-(diphenylphosphino)-N-(2-pyridinylmethyl)ethanamine]ruthenium(II)

greener alternative

97%

别名:

Ru-PNN catalyst

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About This Item

经验公式(希尔记法):
C38H36Cl2N2P2Ru
MDL號碼:
分類程式碼代碼:
12161600
PubChem物質ID:
NACRES:
NA.22

化驗

97%

形狀

solid

反應適用性

core: ruthenium
reagent type: catalyst

環保替代產品特色

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

275-295 °C

環保替代類別

SMILES 字串

Cl[Ru]Cl.[H]N(CCP(C1=CC=CC=C1)C2=CC=CC=C2)CC3=NC=CC=C3.P(C4=CC=CC=C4)(C5=CC=CC=C5)C6=CC=CC=C6

InChI

1S/C20H21N2P.C18H15P.2ClH.Ru/c1-3-10-19(11-4-1)23(20-12-5-2-6-13-20)16-15-21-17-18-9-7-8-14-22-18;1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h1-14,21H,15-17H2;1-15H;2*1H;/q;;;;+2/p-2

InChI 密鑰

JFYJJNHKCBDTMZ-UHFFFAOYSA-L

一般說明

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

應用

Catalyst for hydrogenation of esters to alcohols. Greener alternative to stoichiometric hydride reagents.

From Esters to Alcohols and Back with Ruthenium and Osmium Catalysts

法律資訊

This Product is licensed from GreenCentre Canada for non-commercial, research use only. Please contact GreenCentre Canada for information regarding commercial use of Product.

象形圖

Skull and crossbones

訊號詞

Danger

危險聲明

危險分類

Acute Tox. 3 Inhalation - Acute Tox. 4 Dermal - Acute Tox. 4 Oral

儲存類別代碼

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable


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其他客户在看

Slide 1 of 1

1 of 1

Spasyuk, D.;
Angewandte Chemie (International Edition in English), 2772-2772 (2012)

商品

Learn about Ester Hydrogenation from MilliporeSigma. The reduction of esters to alcohols is typically accomplished using metal hydrides. While effective, it comes at the cost of stoichiometric waste and complicated workup procedures.

Learn about Ester Hydrogenation from MilliporeSigma. The reduction of esters to alcohols is typically accomplished using metal hydrides. While effective, it comes at the cost of stoichiometric waste and complicated workup procedures.

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