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Merck

723142

Sigma-Aldrich

三[2-(二甲氨基)乙基]胺

97%

别名:

Me6TREN

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About This Item

经验公式(希尔记法):
C12H30N4
CAS号:
分子量:
230.39
MDL號碼:
分類程式碼代碼:
12162002
PubChem物質ID:
NACRES:
NA.23

品質等級

化驗

97%

形狀

liquid

折射率

n20/D 1.455

密度

0.862 g/mL at 25 °C

SMILES 字串

CN(C)CCN(CCN(C)C)CCN(C)C

InChI

1S/C12H30N4/c1-13(2)7-10-16(11-8-14(3)4)12-9-15(5)6/h7-12H2,1-6H3

InChI 密鑰

VMGSQCIDWAUGLQ-UHFFFAOYSA-N

一般說明

三[2-(二甲基氨基)乙基]胺(Me6TREN)是形成四齿配体的脂肪族叔胺。这种成分主要用于原子转移自由基聚合(ATRP)。它是(2-氨基乙基)胺的六甲基衍生物,也称为trenMe。可通过修饰Ristempart合成制备这一成分。

應用

Me6TREN与铜化合物形成络合物,可用作金属酶氧化还原反应中的配体。
用于生产遥爪聚合物的原子转移自由基聚合反应(ATRP)配体。

象形圖

Corrosion

訊號詞

Danger

危險聲明

危險分類

Eye Dam. 1 - Skin Corr. 1B

儲存類別代碼

8A - Combustible corrosive hazardous materials

水污染物質分類(WGK)

WGK 3

閃點(°F)

219.9 °F - closed cup

閃點(°C)

104.4 °C - closed cup


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分析证书(COA)

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Xia Song et al.
Biomacromolecules, 17(12), 3957-3963 (2016-10-25)
Paclitaxel (PTX), a hydrophobic anticancer drug, is facing several clinical limitations such as low bioavailability and drug resistance. To solve the problems, a well-defined β-cyclodextrin-poly(N-isopropylacrylamide) star polymer was synthesized and used as a nanocarrier to improve the water solubility and
Expanding the scope of the photoinduced living radical polymerization of acrylates in the presence of CuBr2 and Me6-Tren
Anastasaki A, et al.
Macromolecules, 47(12), 3852-3859 (2014)
Tsarevsky, N. V.; Braunecker, W. A.; Brooks, S. J.; Matyjaszewski, K.
Marcromolecules, 39, 6817-6817 (2006)
Reversible Binding of Dioxygen by a Copper (I) Complex with Tris (2-dimethylaminoethyl) amine (Me6tren) as a Ligand
Becker M, et al.
Chemistry?A European Journal, 5(11), 3124-3129 (1999)
Optimization of atom transfer radical polymerization using Cu (I)/tris (2-(dimethylamino) ethyl) amine as a catalyst
Queffelec J, et al.
Macromolecules, 33(23), 8629-8639 (2000)

商品

Tools and techniques for performing atom transfer radical polymerization (ATRP) with benefits and limitations.

Atom transfer radical polymerization (ATRP) has emerged as one of the most successful synthetic techniques for the preparation of polymers with predetermined molecular weights, narrow molecular weight distributions, and high degrees of chain end functionalities.

ATRP polymerization, chain transfer agent, living polymerization, functional telechelic polymers

Find how atom transfer radical polymerization (ATRP) tools can be used for the synthesis of well-defined functionalized polymers.

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实验方案

Sigma-Aldrich presents an article about RAFT, or Reversible Addition/Fragmentation Chain Transfer, which is a form of living radical polymerization.

We presents an article featuring procedures that describe polymerization of methyl methacrylate and vinyl acetate homopolymers and a block copolymer as performed by researchers at CSIRO.

Sigma-Aldrich presents an article about the typical procedures for polymerizing via ATRP, which demonstrates that in the following two procedures describe two ATRP polymerization reactions as performed by Prof. Dave Hadddleton′s research group at the University of Warwick.

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