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Sigma-Aldrich

α-溴异丁酰溴

98%

别名:

2-溴-2-甲基丙酰溴, BIBB

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About This Item

线性分子式:
(CH3)2CBrCOBr
CAS号:
20769-85-1
分子量:
229.90
Beilstein:
1746128
EC號碼:
244-017-3
MDL號碼:
MFCD00000122
分類程式碼代碼:
12352100
PubChem物質ID:
24855196
NACRES:
NA.22

化驗

98%

形狀

liquid

折射率

n20/D 1.507 (lit.)

bp

162-164 °C (lit.)

密度

1.86 g/mL at 25 °C (lit.)

SMILES 字串

CC(C)(Br)C(Br)=O

InChI

1S/C4H6Br2O/c1-4(2,6)3(5)7/h1-2H3

InChI 密鑰

YOCIJWAHRAJQFT-UHFFFAOYSA-N

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相关类别

一般說明

BIBB是合成酰胺、大环酰胺、烯酮和炔酮的重要试剂。

應用

α-溴异丁酰溴已用于：
  • 作为原子转移自由基聚合（ATRP）引发剂，用于氧化石墨烯表面上羟基的官能化
  • 形成一个 N保护的卤代二烯酰胺，在铜（I）和叔胺存在下提供四元和五元内酰胺
  • 通过与低聚己内酯二醇反应制备聚己内酯大分子引发剂 通过与固定在外表面的ATRP引发剂反应制备介孔二氧化硅纳米粒子

象形圖

Corrosion
GHS05

訊號詞

Danger

危險聲明

H314

危險分類

Eye Dam. 1 - Skin Corr. 1B

儲存類別代碼

8A - Combustible corrosive hazardous materials

水污染物質分類（WGK）

WGK 3

閃點（°F）

>230.0 °F

閃點（°C）

> 110 °C

個人防護裝備

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

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Shih-Jer Huang et al.
International journal of nanomedicine, 8, 2011-2027 (2013-06-08)
Cationic polymers are one of the major nonviral gene delivery vectors investigated in the past decade. In this study, we synthesized several cationic copolymers using atom transfer radical polymerization (ATRP) for gene delivery vectors: pluronic F127-poly(dimethylaminoethyl methacrylate) (PF127-pDMAEMA), pluronic F127-poly
Ya'nan Deng et al.
Mikrochimica acta, 185(8), 370-370 (2018-07-11)
Poly(2-naphthyl acrylate) was first grafted onto silica-coated magnetic nanoparticles by surface-initiated atom transfer radical polymerization to prepare a reversed-phase magnetic adsorbent. The resulting polymer brush displays enhanced extraction efficiency by offering active sites on the surfaces of adsorbent. It was
Nicklas N Poulsen et al.
Journal of separation science, 40(3), 779-788 (2016-11-22)
Many bioanalytical methods rely on electrophoretic separation of structurally labile and surface active biomolecules such as proteins and peptides. Often poor separation efficiency is due to surface adsorption processes leading to protein denaturation and surface fouling in the separation channel.
Sun Hwa Lee et al.
Macromolecular rapid communications, 31(3), 281-288 (2010-02-02)
A method for growing polymers directly from the surface of graphene oxide is demonstrated. The technique involves the covalent attachment of an initiator followed by the polymerization of styrene, methyl methacrylate, or butyl acrylate using atom transfer radical polymerization (ATRP).
Andrew J Clark et al.
The Journal of organic chemistry, 72(15), 5923-5926 (2007-07-03)
Reaction of 2-substituted dienamides with catalytic amounts of copper halide/tripyridylamine (TPA) furnishes either 5-exo or 6-endo products with the outcome dependent upon the radical initiating unit. Reaction of 3-substituted dienamides produces beta-lactams via a 4-exo cyclization with termination of the
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