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![三[2-(二甲氨基)乙基]胺 97%](/deepweb/assets/sigmaaldrich/product/structures/695/792/ee0ff167-22a3-43a7-83a1-6c4908adf0ae/640/ee0ff167-22a3-43a7-83a1-6c4908adf0ae.png)
一般說明
可以通过还原溴化铜或CuSO4-NaBr来制备溴化亚铜。在熔融状态下，它呈灰褐色/绿褐色。
應用
一些已报道的溴化铜应用包括：
据报道，其可在CuBr/LiOCH3（甲醇溶液）存在下，将 α-溴- α-氯代羧酸盐还原均耦联为 α, α′二氯琥珀酸二甲酯衍生物。
- 交叉偶联反应中的催化剂。
- Sonogashira耦合中的助催化剂。
- 在炔烃对映选择性加成中的Lewis酸。
- 当与三分子吡啶引发剂进行络合时充当还原剂，从而用于苯乙烯、丙烯酸甲酯和甲基丙烯酸甲酯的受控聚合。
据报道，其可在CuBr/LiOCH3（甲醇溶液）存在下，将 α-溴- α-氯代羧酸盐还原均耦联为 α, α′二氯琥珀酸二甲酯衍生物。
相關產品
产品编号
说明
价格
訊號詞
Danger
危險聲明
危險分類
Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Corr. 1B
儲存類別代碼
8A - Combustible corrosive hazardous materials
水污染物質分類（WGK）
WGK 3
個人防護裝備
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
其他客户在看
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Synthesis, 1535-1535 (2007)
Denissova I and Barriault L
Handbook of Reagents for Organic Synthesis null
Lu-Ying Han et al.
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Polymers, 11(8) (2019-07-31)
Atom transfer radical polymerization (ATRP) of methyl acrylate (MA) was carried out by continuous feeding of Cu(I) activators. Typically, the solvent, the monomer, the initiator, and the CuBr2/Me6TREN deactivator are placed in a Schlenk flask (Me6TREN: tris[2-(dimethylamino)ethyl]amine), while the CuBr/Me6TREN
实验方案
We presents an article about ARGET ATRP, and its procedure for PMMA polymer brush growth. Surface preparation before polymer brush growth consists of two steps: surface cleaning and initiator monolayer deposition.
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