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699616

Sigma-Aldrich

氯[三(2,4-二叔丁基苯基)亚磷酸]金

别名:

[三(2,4-二叔丁基苯基)亚磷酸]氯化金

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About This Item

经验公式（希尔记法）:
C42H63AuClO3P
CAS号:
915299-24-0
分子量:
879.34
MDL號碼:
MFCD11045473
分類程式碼代碼:
12161600
PubChem物質ID:
329762147
NACRES:
NA.22

形狀

powder

品質等級

100

反應適用性

core: gold
reagent type: catalyst

mp

200-202 °C

SMILES 字串

Cl[Au].CC(C)(C)c1ccc(OP(Oc2ccc(cc2C(C)(C)C)C(C)(C)C)Oc3ccc(cc3C(C)(C)C)C(C)(C)C)c(c1)C(C)(C)C

InChI

1S/C42H63O3P.Au.ClH/c1-37(2,3)28-19-22-34(31(25-28)40(10,11)12)43-46(44-35-23-20-29(38(4,5)6)26-32(35)41(13,14)15)45-36-24-21-30(39(7,8)9)27-33(36)42(16,17)18;;/h19-27H,1-18H3;;1H/q;+1;/p-1

InChI 密鑰

GCWCLHMEYZKZRO-UHFFFAOYSA-M

相关类别

應用

Gold Catalysts — 21st Century ′Gold Rush′

  • Intermolecular addition of carbon nucleophiles to 1,5 and 1,6 enynes
Catalyst for:
  • [4C+2C] cycloadditions
  • Cis-selective single-cleavagte skeletal cycloisomerization
  • Diastereoselective Au-catalyzed intermolecular cyclopropanation
  • Elucidating the mechanism of "endocyclic" skeletal rearrangement of 1,6-enynes
  • Addition reactions

象形圖

Exclamation mark
GHS07

訊號詞

Warning

危險聲明

H315,H319,H335

危險分類

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

11 - Combustible Solids

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

個人防護裝備

dust mask type N95 (US), Eyeshields, Gloves

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分析证书(COA)

Lot/Batch Number
SHBN6138
SHBJ8229
14431CJ

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Catelijne H M Amijs et al.
The Journal of organic chemistry, 73(19), 7721-7730 (2008-09-02)
Gold(I)-catalyzed addition of carbon nucleophiles to 1,6-enynes gives two different type of products by reaction at the cyclopropane or at the carbene carbons of the intermediate cyclopropyl gold carbenes. The 5-exo-dig cyclization is followed by most 1,6-enynes, although those bearing

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We are proud to offer a treasure-trove of gold precatalysts and silver salts, as well as an extensive portfolio of unsaturated building blocks to accelerate your research success in this exciting field.

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