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About This Item
线性分子式:
C4H8O2 · BHCl2
CAS号:
分子量:
170.83
MDL號碼:
分類程式碼代碼:
12352005
PubChem物質ID:
NACRES:
NA.22
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反應適用性
reagent type: reductant
品質等級
濃度
3 M in methylene chloride
密度
1.321 g/mL at 25 °C
官能基
ether
儲存溫度
2-8°C
SMILES 字串
Cl[BH-](Cl)[O+]1CCOCC1
InChI
1S/C4H9BCl2O2/c6-5(7)9-3-1-8-2-4-9/h5H,1-4H2
InChI 密鑰
RCKKTUSYECYDLY-UHFFFAOYSA-N
應用
Reactant for:
- Hydroboration reactions
- Preparation of alkenyl- and alkylboronic acids
可易于代替常用硼氢化试剂，例如 BH3、THF 和 BMS。
法律資訊
U.S. Pat. No. 6,008,414
訊號詞
Danger
危險聲明
危險分類
Carc. 2 - Eye Dam. 1 - Skin Corr. 1B - STOT SE 3
標靶器官
Central nervous system
安全危害
儲存類別代碼
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
水污染物質分類（WGK）
WGK 3
閃點（°F）
221.0 °F - closed cup
閃點（°C）
105 °C - closed cup
J V Kanth et al.
The Journal of organic chemistry, 66(16), 5359-5365 (2001-08-04)
Several less volatile oxygen-containing Lewis bases, such as tert-butyl methyl ether, dioxane, anisole, ethyl acetate, beta-chloroethyl ether, and monoglyme, were examined as prospective mono- and dichloroborane carriers. Dioxane, ethyl acetate, and beta-chloroethyl ether form relatively stable boron trichloride adducts, but
Kanth, J. V. B.; Brown, H. C.
Organic Letters, 1, 315-315 (1999)
Josyula, K. V. B. et al
Tetrahedron Letters, 44, 7789-7789 (2003)
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