255106

二溴硼烷甲硫醚络合物

• 别名: 二溴甲基硫醚化硼络合物
• 线性分子式: (CH₃)₂S · BHBr₂
• CAS号: 55671-55-1
• 分子量: 233.76
• Beilstein: 4449985
• MDL號碼: MFCD00011601
• 分類程式碼代碼: 12352112
• PubChem物質ID: 24855287
• NACRES: NA.22

属性

• 形狀: solid
• 反應適用性: reagent type: reductant
• mp: 30-35 °C (lit.)
• SMILES 字串: CSC.BrBBr
• InChI: 1S/C2H6S.BBr2H/c1-3-2;2-1-3/h1-2H3;1H
• InChI 密鑰: PGSRDLGPKTVELT-UHFFFAOYSA-N

说明

應用

Reactant for:

• Reductive elimination C-C bond forming reactions
• Lithiation-borylation reaction with Hoppe′s lithiated carbamates
• Preparation of boron analogues of uracil
• Boronation reactions for formation of cyclic boronium salts
• Hydroboration reactions
• Ring opening of terminal epoxides

安全信息

• 象形圖: GHS02,GHS05
• 訊號詞: Danger
• 危險聲明: H228,H261,H314
• 防範說明: P210 - P231 + P232 - P260 - P280 - P303 + P361 + P353 - P305 + P351 + P338
• 危險分類: Flam. Sol. 1 - Skin Corr. 1B - Water-react 2
• 安全危害: EUH014
• 儲存類別代碼: 4.3 - Hazardous materials which set free flammable gases upon contact with water
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: 78.8 °F - closed cup
• 閃點（°C）: 26 °C - closed cup
• 個人防護裝備: Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges