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化驗
97%
mp
26-30 °C (lit.)
官能基
bromo
chloro
SMILES 字串
Clc1ccc(Br)c(Cl)c1
InChI
1S/C6H3BrCl2/c7-5-2-1-4(8)3-6(5)9/h1-3H
InChI 密鑰
ISHYFWKKWKXXPL-UHFFFAOYSA-N
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一般說明
1-Bromo-2,4-dichlorobenzene is an aryl halide. It can be distinguished from the other bromodichlorobenzene isomers using IR and Raman spectral data. It can undergo Suzuki–Miyaura cross-coupling reaction with arylboronic acids in the presence of different Suzuki catalysts.
訊號詞
Warning
危險聲明
危險分類
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
標靶器官
Respiratory system
儲存類別代碼
10 - Combustible liquids
水污染物質分類（WGK）
WGK 3
閃點（°F）
208.4 °F - closed cup
閃點（°C）
98 °C - closed cup
個人防護裝備
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
The 1,3-Diaminobenzene-Derived Aminophosphine Palladium Pincer Complex {C6H3[NHP(piperidinyl)2]2Pd(Cl)}-A Highly Active Suzuki-Miyaura Catalyst with Excellent Functional Group Tolerance.
Bolliger JL and Frech CM.
Advanced Synthesis & Catalysis, 352(6), 1075-1080 (2010)
Jeanne L Bolliger et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 16(13), 4075-4081 (2010-02-27)
Dichloro-bis(aminophosphine) complexes are stable depot forms of palladium nanoparticles and have proved to be excellent Suzuki-Miyaura catalysts. Simple modifications of the ligand (and/or the addition of water to the reaction mixture) have allowed their formation to be controlled. Dichlorobis[1-(dicyclohexylphosphanyl)piperidine]palladium (3)
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