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About This Item
线性分子式:
(C6F5O)2CO
CAS号:
分子量:
394.12
Beilstein:
2029727
MDL號碼:
分類程式碼代碼:
12352101
PubChem物質ID:
NACRES:
NA.22
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product name
双(五氟苯基)碳酸酯, 97%
品質等級
化驗
97%
反應適用性
reaction type: Carbonylations
mp
47-50 °C (lit.)
應用
peptide synthesis
SMILES 字串
Fc1c(F)c(F)c(OC(=O)Oc2c(F)c(F)c(F)c(F)c2F)c(F)c1F
InChI
1S/C13F10O3/c14-1-3(16)7(20)11(8(21)4(1)17)25-13(24)26-12-9(22)5(18)2(15)6(19)10(12)23
InChI 密鑰
IOVVFSGCNWQFQT-UHFFFAOYSA-N
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一般說明
双(五氟苯基)碳酸酯相当于羰基化合物，常用于偶联反应。它可用作氮杂肽制备试剂。
應用
双(五氟苯基)碳酸酯可用于制备：
- 一种名为6,6′-(乙烷-1,2-二基)双(1,3,6-二氧杂环辛-2-酮)的环状碳酸酯，是合成非异氰酸酯聚氨酯的关键中间体。
- 一种基于香豆素的脂肪族聚碳酸酯，名为5-(4-甲基伞形酮氧基羰基)-5-甲基-1,3-二氧己环-2-酮 (MUC)。
儲存類別代碼
11 - Combustible Solids
水污染物質分類（WGK）
WGK 3
閃點（°F）
230.0 °F - closed cup
閃點（°C）
110 °C - closed cup
個人防護裝備
Eyeshields, Gloves, type N95 (US)
其他客户在看
[Dipentafluorophenylcarbonate in the synthesis of oligonucleotides by the H-phosphonate method].
V A Efimov et al.
Bioorganicheskaia khimiia, 20(3), 323-326 (1994-03-01)
Bis(pentafluorophenyl)carbonate
Encyclopedia of Reagents for Organic Synthesis, Second Edition (2004)
Dipentafluorophenyl carbonate--a reagent for the synthesis of oligonucleotides and their conjugates.
V A Efimov et al.
Nucleic acids research, 21(23), 5337-5344 (1993-11-25)
Dipentafluorophenyl carbonate has been successfully used as condensing agent for the internucleotide bond formation in the synthesis of oligonucleotides via H-phosphonate approach. The mechanism of a nucleotide component activation with this reagent has been investigated with the help of 31P
V N Medvedkin et al.
Bioorganicheskaia khimiia, 15(4), 460-464 (1989-04-01)
Dipentafluorophenylcarbonate, belonging to transesterifiying reagents, has been prepared and used for the synthesis of pentafluorophenyl esters of amino acids. In contrast to many other reagents of the kind, its preparation is simple, it is highly reactive and at the same
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