529680

氯化亚锰 水合物

99.999% trace metals basis

• 别名: Manganese chloride hydrate
• 线性分子式: MnCl₂ · xH₂O
• CAS号: 73913-06-1
• 分子量: 125.84 (anhydrous basis)
• EC號碼: 231-869-6
• MDL號碼: MFCD00149793
• 分類程式碼代碼: 12161600
• PubChem物質ID: 24877701
• NACRES: NA.22

属性

• 化驗: 99.999% trace metals basis
• 反應適用性: core: manganese; reagent type: catalyst
• mp: 122 °C (lit.)
• 密度: 1.913 g/mL at 25 °C (lit.)
• 儲存溫度: 2-8°C
• SMILES 字串: O.Cl[Mn]Cl
• InChI: 1S/2ClH.Mn.H2O/h2*1H;;1H2/q;;+2;/p-2
• InChI 密鑰: BXRRQHBNBXJZBQ-UHFFFAOYSA-L

说明

應用

Starting material for preparation of organomanganese chloride reagents; Catalyst for reductionof vinyl and aryl halides, stereoselective coupling of vinyl iodides, and alkylation of enol triflates; also used for Mn-Cu-catalyzed conjugate addition of RMgX to enones and for Mn-catalyzed acylation of RMgX by acyl chlorides; in combination with NaBH4 is diastereoselective reducing agent; starting material for the preparation of Mn enolates regio- and stereo-selectively.

安全信息

• 象形圖: GHS06,GHS08,GHS09
• 訊號詞: Danger
• 危險聲明: H301,H319,H373,H411
• 防範說明: P260 - P264 - P273 - P301 + P310 - P305 + P351 + P338 - P314
• 危險分類: Acute Tox. 3 Oral - Aquatic Chronic 2 - Eye Irrit. 2 - STOT RE 2
• 標靶器官: Brain
• 儲存類別代碼: 6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• 水污染物質分類（WGK）: WGK 2
• 閃點（°F）: Not applicable
• 閃點（°C）: Not applicable
• 個人防護裝備: dust mask type N95 (US), Eyeshields, Gloves