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等級
anhydrous
化驗
≥99.9% trace metals basis
形狀
powder
反應適用性
reagent type: catalyst
core: samarium
reagent type: reductant
雜質
≤1000.0 ppm Trace Rare Earth Analysis
SMILES 字串
I[Sm]I
InChI
1S/2HI.Sm/h2*1H;/q;;+2/p-2
InChI 密鑰
UAWABSHMGXMCRK-UHFFFAOYSA-L
應用
在 THF/HMPA 中和室温下以良好至优异的产率促进醛的氰氟化,从而生成氰氟醇。
儲存類別代碼
11 - Combustible Solids
水污染物質分類(WGK)
WGK 3
閃點(°F)
Not applicable
閃點(°C)
Not applicable
個人防護裝備
Eyeshields, Gloves, type N95 (US)
Synthesis, 1309-1309 (2007)
Martin Holan et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 21(27), 9877-9888 (2015-05-28)
Densely functionalized cyclopentane derivatives with up to four consecutive stereocenters are assembled by a tandem Michael addition/single-electron transfer oxidation/radical cyclization/oxygenation strategy mediated by ferrocenium hexafluorophosphate, a recyclable, less toxic single-electron transfer oxidant. Ester enolates were coupled with α-benzylidene and α-alkylidene
商品
An article regarding Leighton’s Chiral Allylation Reagents.
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