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化驗
99%
bp
70 °C/2 mmHg (lit.)
mp
45-47 °C (lit.)
SMILES 字串
FC(F)(F)c1cc[nH]n1
InChI
1S/C4H3F3N2/c5-4(6,7)3-1-2-8-9-3/h1-2H,(H,8,9)
InChI 密鑰
PYXNITNKYBLBMW-UHFFFAOYSA-N
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一般說明
3-(三氟甲基)吡唑是一种杂环结构单元。它在 DMF 中与烷基碘进行烷基化,得到 N-烷基吡唑。它参与二取代嘧啶的合成。
應用
3-(三氟甲基)吡唑可用于铜催化的吡唑 N-芳基化。可用于与硼氢化钠加热合成氢化三(1H-3-三氟甲基吡唑-1-基)硼酸钠。
訊號詞
Warning
危險聲明
危險分類
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
標靶器官
Respiratory system
儲存類別代碼
11 - Combustible Solids
水污染物質分類(WGK)
WGK 3
閃點(°F)
Not applicable
閃點(°C)
Not applicable
個人防護裝備
dust mask type N95 (US), Eyeshields, Gloves
[A simple method for the direct preparation of O2,3'-cyclo-2'-desoxynucleosides].
Tetrahedron letters, 44(44), 3863-3865 (1969-09-01)
The effect of the 3-trifluoromethyl substituent in polypyrazolylborato complexes on the iron(II) spin state; X-ray diffraction and absorption and Mossbauer studies.
Inorgorganica Chimica Acta, 318(1), 67-76 (2001)
Mild Conditions for Copper-Catalysed N-Arylation of Pyrazoles.
European Journal of Organic Chemistry, 4, 695-709 (2004)
Organic letters, 5(7), 1011-1013 (2003-03-28)
[reaction: see text] The fluorous synthesis of disubstituted pyrimidines is carried out by attaching 2,4-dichloro-6-methylpyrimidine with 1H,1H,2H,2H-perfluorodecanethiol. The tagged substrate is substituted with 3-(trifluoromethyl)pyrazole followed by thioether oxidation and tag displacement with amines or thiols. The fluorous chain serves as
Bioorganic & medicinal chemistry letters, 15(22), 4898-4906 (2005-09-17)
A novel class of anthranilic diamides has been discovered with exceptional insecticidal activity on a range of Lepidoptera. These compounds have been found to exhibit their action by release of intracellular Ca2+ stores mediated by the ryanodine receptor. The discovery
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