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品質等級
化驗
96%
形狀
liquid
折射率
n20/D 1.422 (lit.)
bp
70-72 °C/2 mmHg (lit.)
密度
1.012 g/mL at 25 °C (lit.)
SMILES 字串
COC(CCCC(=O)OC)OC
InChI
1S/C8H16O4/c1-10-7(9)5-4-6-8(11-2)12-3/h8H,4-6H2,1-3H3
InChI 密鑰
YOFAONQHOIRLCQ-UHFFFAOYSA-N
一般說明
Methyl 5,5-dimethoxyvalerate (methyl 5,5-dimethoxypentanoate) is an ester. It can be prepared by reacting methyl 5-oxopentanoate with p-toluene sulfonic acid and trimethylorthoformate. It participates in the synthesis of 1-palmitoyl-2-(5-oxovaleroyl)-sn-glycero-3-phosphatidylcholine.
應用
Methyl 5,5-dimethoxyvalerate may be employed in the synthesis of seven-membered carbocycles. It may be used in the synthesis of 5-(phenylamino)-4-(phenylimino)methyl)-4-pentenoic acid derivatives.
訊號詞
Warning
危險分類
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
標靶器官
Respiratory system
儲存類別代碼
10 - Combustible liquids
水污染物質分類(WGK)
WGK 3
閃點(°F)
145.4 °F - closed cup
閃點(°C)
63 °C - closed cup
個人防護裝備
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
The Journal of biological chemistry, 279(51), 53395-53406 (2004-10-07)
Oxidation of unsaturated phospholipids results in the generation of aldehyde side chains that remain esterified to the phospholipid backbone. Such "core" aldehydes elicit immune responses and promote inflammation. However, the biochemical mechanisms by which phospholipid aldehydes are metabolized or detoxified
Bioconjugate chemistry, 19(12), 2487-2491 (2008-12-05)
A facile synthetic route to prepare monofunctional carbocyanine dyes for biological application is developed. Three pentamethine carbocyanine dyes have been successfully modified with a variety of functional groups such as: carboxylic acids, azides, or alkynes. The new dyes are characterized
Formation of seven-membered carbocycles by the use of cyclopropyl silyl ethers as homoenols.
Angewandte Chemie (International ed. in English), 45(30), 4988-4991 (2006-07-05)
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