所有图片(3)
About This Item
线性分子式:
C6H10(NH2)2
CAS号:
分子量:
114.19
Beilstein:
2801645
MDL號碼:
分類程式碼代碼:
12352116
PubChem物質ID:
NACRES:
NA.22
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化驗
98%
形狀
solid
光學活性
[α]20/D +25°, c = 5 in 1 M HCl
光學純度
ee: 99% (GLC)
bp
104-110 °C/40 mmHg (lit.)
mp
40-43 °C (lit.)
SMILES 字串
N[C@H]1CCCC[C@@H]1N
InChI
1S/C6H14N2/c7-5-3-1-2-4-6(5)8/h5-6H,1-4,7-8H2/t5-,6-/m0/s1
InChI 密鑰
SSJXIUAHEKJCMH-WDSKDSINSA-N
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應用
用于形成金属络合物的多功能配体。用于合成在不对称催化中具有应用潜力的手性 tropocoronand。
訊號詞
Danger
危險聲明
危險分類
Eye Dam. 1 - Skin Corr. 1B
儲存類別代碼
8A - Combustible corrosive hazardous materials
水污染物質分類(WGK)
WGK 3
閃點(°F)
158.0 °F - closed cup
閃點(°C)
70 °C - closed cup
個人防護裝備
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Chenier, P.J. et al.
Tetrahedron Letters, 38, 7341-7341 (1997)
Mukaiyama, T.
Aldrichimica Acta, 29, 59-59 (1996)
Design principles of chiral carbon nanodots help convey chirality from molecular to nanoscale level.
Luka Ðorđević et al.
Nature communications, 9(1), 3442-3442 (2018-08-26)
The chirality of (nano)structures is paramount in many phenomena, including biological processes, self-assembly, enantioselective reactions, and light or electron spin polarization. In the quest for new chiral materials, metallo-organic hybrids have been attractive candidates for exploiting the aforementioned scientific fields.
Takuya Kurahashi et al.
Journal of the American Chemical Society, 131(34), 12394-12405 (2009-08-27)
A series of Mn(IV)(salen)(L)(2) complexes bearing different external axial ligands (L = Cl, NO(3), N(3), and OCH(2)CF(3)) from chiral salen ligands with trans-cyclohexane-1,2-diamine as a chiral scaffold are synthesized, to gain insight into conformational properties of metal salen complexes. X-ray
Kui Mei et al.
Organic letters, 11(13), 2864-2867 (2009-06-03)
A highly enantioselective conjugate addition of nitroalkanes to enones has been developed. The process is efficiently catalyzed by a simple chiral cyclohexanediamine-derived primary amine thiourea with a broad substrate scope.
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