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Merck

346713

Sigma-Aldrich

(1S,2S)-(+)-1,2-环己二胺

98%

别名:

(1S)-反式-1,2-二氨基环己烷, (1S)-反式-1,2-环己二胺

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About This Item

线性分子式:
C6H10(NH2)2
CAS号:
分子量:
114.19
Beilstein:
2801645
MDL號碼:
分類程式碼代碼:
12352116
PubChem物質ID:
NACRES:
NA.22

化驗

98%

形狀

solid

光學活性

[α]20/D +25°, c = 5 in 1 M HCl

光學純度

ee: 99% (GLC)

bp

104-110 °C/40 mmHg (lit.)

mp

40-43 °C (lit.)

SMILES 字串

N[C@H]1CCCC[C@@H]1N

InChI

1S/C6H14N2/c7-5-3-1-2-4-6(5)8/h5-6H,1-4,7-8H2/t5-,6-/m0/s1

InChI 密鑰

SSJXIUAHEKJCMH-WDSKDSINSA-N

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應用

用于形成金属络合物的多功能配体。用于合成在不对称催化中具有应用潜力的手性 tropocoronand。

象形圖

Corrosion

訊號詞

Danger

危險聲明

危險分類

Eye Dam. 1 - Skin Corr. 1B

儲存類別代碼

8A - Combustible corrosive hazardous materials

水污染物質分類(WGK)

WGK 3

閃點(°F)

158.0 °F - closed cup

閃點(°C)

70 °C - closed cup

個人防護裝備

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Chenier, P.J. et al.
Tetrahedron Letters, 38, 7341-7341 (1997)
Mukaiyama, T.
Aldrichimica Acta, 29, 59-59 (1996)
Luka Ðorđević et al.
Nature communications, 9(1), 3442-3442 (2018-08-26)
The chirality of (nano)structures is paramount in many phenomena, including biological processes, self-assembly, enantioselective reactions, and light or electron spin polarization. In the quest for new chiral materials, metallo-organic hybrids have been attractive candidates for exploiting the aforementioned scientific fields.
Takuya Kurahashi et al.
Journal of the American Chemical Society, 131(34), 12394-12405 (2009-08-27)
A series of Mn(IV)(salen)(L)(2) complexes bearing different external axial ligands (L = Cl, NO(3), N(3), and OCH(2)CF(3)) from chiral salen ligands with trans-cyclohexane-1,2-diamine as a chiral scaffold are synthesized, to gain insight into conformational properties of metal salen complexes. X-ray
Kui Mei et al.
Organic letters, 11(13), 2864-2867 (2009-06-03)
A highly enantioselective conjugate addition of nitroalkanes to enones has been developed. The process is efficiently catalyzed by a simple chiral cyclohexanediamine-derived primary amine thiourea with a broad substrate scope.

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