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Merck

340928

Sigma-Aldrich

1,4-酐-赤藓糖醇

95%

别名:

(3R,4S)-四氢-3,4-呋喃二醇, 赤藓醇-1,4-酸酐, 间-3,4-二羟基四氢呋喃, 顺-(3R,4S)-四氢-3,4-呋喃二醇, 顺式-3,4-二羟基四氢呋喃, 顺式-四氢呋喃-3,4-二醇

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About This Item

经验公式(希尔记法):
C4H8O3
CAS号:
分子量:
104.10
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

品質等級

化驗

95%

形狀

liquid

折射率

n20/D 1.477 (lit.)

密度

1.27 g/mL at 25 °C (lit.)

官能基

ether
hydroxyl

SMILES 字串

O[C@H]1COC[C@H]1O

InChI

1S/C4H8O3/c5-3-1-7-2-4(3)6/h3-6H,1-2H2/t3-,4+

InChI 密鑰

SSYDTHANSGMJTP-ZXZARUISSA-N

一般說明

1,4-脱水赤醇是一种环状邻位二醇。 1,4-脱水赤醇在氧化钨-钯催化剂上发生加氢脱氧反应,得到3-羟基四氢呋喃。

應用

1,4-脱水赤醇被用于合成缺少腺嘌呤成分的腺苷A的吡喃葡萄糖苷类似物的关键步骤。

儲存類別代碼

10 - Combustible liquids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

Eyeshields, Gloves


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分析证书(COA)

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Yasushi Amada et al.
ChemSusChem, 7(8), 2185-2192 (2014-07-01)
Hydrodeoxygenation of cyclic vicinal diols such as 1,4-anhydroerythritol was conducted over catalysts containing both a noble metal and a group 5-7 transition-metal oxide. The combination of Pd and WOx allowed the removal of one of the two OH groups selectively.
Andrew M Riley et al.
Carbohydrate research, 337(12), 1067-1082 (2002-06-14)
Adenophostins A and B are naturally occurring glyconucleotides that interact potently with receptors for D-myo-inositol 1,4,5-trisphosphate, an important second messenger molecule in most cell types. Here we describe the design and synthesis of glucopyranoside-based analogues of adenophostin A lacking the
Alex C Watanabe et al.
Environmental science & technology, 52(15), 8346-8354 (2018-06-29)
Laboratory and field measurements have demonstrated that isoprene epoxydiol (IEPOX) is the base component of a wide range of chemical species found in isoprene-derived secondary organic aerosol (SOA). To address newly raised questions concerning the chemical identities of IEPOX-derived SOA
Aritomo Yamaguchi et al.
Physical chemistry chemical physics : PCCP, 19(4), 2714-2722 (2016-11-30)
The intramolecular dehydration of biomass-derived sugar alcohols d-sorbitol, d-mannitol, galactitol, xylitol, ribitol, l-arabitol, erythritol, l-threitol, and dl-threitol was investigated in high-temperature water at 523-573 K without the addition of any acid catalysts. d-Sorbitol and d-mannitol were dehydrated into isosorbide and

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