224499

叔丁基氯化镁 溶液

2.0 M in diethyl ether

• 别名: t-Butylmagnesium chloride, tert-Butylchloromagnesium, Chloro(1,1-dimethylethyl)magnesium
• 线性分子式: (CH₃)₃CMgCl
• CAS号: 677-22-5
• 分子量: 116.87
• Beilstein: 3535403
• MDL號碼: MFCD00000465
• 分類程式碼代碼: 12352103
• PubChem物質ID: 24853442
• NACRES: NA.22

属性

• 品質等級: 200
• 反應適用性: reaction type: Grignard Reaction
• 濃度: 2.0 M in diethyl ether
• 密度: 0.828 g/mL at 25 °C
• SMILES 字串: CC(C)(C)[Mg]Cl
• InChI: 1S/C4H9.ClH.Mg/c1-4(2)3;;/h1-3H3;1H;/q;;+1/p-1
• InChI 密鑰: ZDRJSYVHDMFHSC-UHFFFAOYSA-M

说明

應用

tert-Butylmagnesium chloride solution can be used as a Grignard reagent:

• In the Fe-catalyzed cross-coupling reaction with chloroenynols.
• To synthesize alkyne-terminated polyhexylthiophenes.

安全信息

• 象形圖: GHS02,GHS05,GHS07
• 訊號詞: Danger
• 危險聲明: H225,H250,H260,H302,H314,H336
• 防範說明: P210 - P231 + P232 - P280 - P303 + P361 + P353 - P305 + P351 + P338 - P370 + P378
• 危險分類: Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Pyr. Liq. 1 - Skin Corr. 1B - STOT SE 3 - Water-react 1
• 標靶器官: Central nervous system
• 安全危害: EUH019
• 儲存類別代碼: 4.2 - Pyrophoric and self-heating hazardous materials
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: -40.0 °F - closed cup
• 閃點（°C）: -40 °C - closed cup
• 個人防護裝備: Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter