所有图片(2)
About This Item
线性分子式:
[(C6H5)2P(CH2)3P(C6H5)2]NiCl2
CAS号:
分子量:
542.04
MDL號碼:
分類程式碼代碼:
12161600
PubChem物質ID:
NACRES:
NA.22
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![[1,2-双(二苯基膦)乙烷]二氯化镍(II)](/deepweb/assets/sigmaaldrich/product/structures/707/956/483e7a6e-5fb5-4e39-abd1-ecf33ccab3cf/640/483e7a6e-5fb5-4e39-abd1-ecf33ccab3cf.png)
![[1,1′-双(二苯基膦)二茂铁]二氯化钯(II)](/deepweb/assets/sigmaaldrich/product/structures/130/734/8846aa26-1858-458a-998d-8c306c13bf0f/640/8846aa26-1858-458a-998d-8c306c13bf0f.png)
形狀
powder
品質等級
反應適用性
core: nickel
reaction type: Cross Couplings
reagent type: catalyst
mp
213 °C (dec.) (lit.)
SMILES 字串
Cl[Ni]Cl.C(CP(c1ccccc1)c2ccccc2)CP(c3ccccc3)c4ccccc4
InChI
1S/C27H26P2.2ClH.Ni/c1-5-14-24(15-6-1)28(25-16-7-2-8-17-25)22-13-23-29(26-18-9-3-10-19-26)27-20-11-4-12-21-27;;;/h1-12,14-21H,13,22-23H2;2*1H;/q;;;+2/p-2
InChI 密鑰
ZBQUMMFUJLOTQC-UHFFFAOYSA-L
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相关类别
應用
[1,3-双(二苯基膦)丙烷]二氯化镍(II)可作为金属富勒烯配合物还原法合成的前体。
以下过程的催化剂：
- 嵌段共聚噻吩的合成
- 卤代芳烃与芳基硼酸的 Suzuki-Miyaura 交叉偶联反应
- 固态复缩聚反应
- 聚（3-烷氧基噻吩）的聚合
- 大环内酯类抗生素 aplyronine A 的 C1-C19 非对映选择性 Nozaki-Hiyama-Kishi 偶联反应
- 共轭聚合物的转移缩聚
相關產品
产品编号
说明
价格
訊號詞
Danger
危險分類
Carc. 1A - Eye Irrit. 2 - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3
標靶器官
Respiratory system
儲存類別代碼
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
水污染物質分類（WGK）
WGK 3
閃點（°F）
Not applicable
閃點（°C）
Not applicable
個人防護裝備
Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
其他客户在看
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A type of graft copolymer based on polysiloxane and regioregular poly(3-hexylthiophene) (P3HT) has been synthesised and its properties have been studied alongside those of its parent conjugated polymer-regioregular P3HT. Electrochemical analysis has revealed more significant changes in conformation of the
Xiaoyu Li et al.
Nature communications, 8, 15909-15909 (2017-06-27)
Micelles formed by the self-assembly of block copolymers in selective solvents have attracted widespread attention and have uses in a wide variety of fields, whereas applications based on their electronic properties are virtually unexplored. Herein we describe studies of solution-processable
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The first comprehensive spectroelectrochemical account of the behaviour of regioregular (RR-P3HT) and statistical (ST-P3HT) poly(3-hexylthiophenes) in solution is presented, in contrast to the many reports dealing with P3HT films merely deposited from solution. The conducted experiments revealed that the two
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Soft matter, 15(25), 5067-5083 (2019-06-12)
The molecular morphology and dynamics of conjugated polymers in the bulk solid state play a significant role in determining macroscopic charge transport properties. To understand this relationship, molecular dynamics (MD) simulations and quantum mechanical calculations are used to evaluate local
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