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應用
- 在正丁基锂的影响下丁二烯和苯乙烯的共聚:该研究探讨了以正丁基锂为催化剂进行的共聚过程,该催化剂对于新合成橡胶材料的开发很重要 (V Bronskaya et al., 2023)。
- 聚丁二烯和苯乙烯-丁二烯橡胶合成中的正丁基锂修饰剂:探讨了正丁基锂和不同修饰剂在工业橡胶合成中的用途,该研究对于理解聚合物性质的控制很重要 (VS Glukhovskoi et al., 2014)。
- 正丁基锂的聚集和溶剂化:考察了正丁基锂在不同溶剂中的聚集行为和溶剂化性质,提供了对于有机合成必不可少的化学相互作用的见解(O Tai et al., 2017)。
其他說明
可能含微量 LiCl。
法律資訊
Kilo-Lab is a registered trademark of Merck KGaA, Darmstadt, Germany
Sure/Seal is a trademark of Sigma-Aldrich Co. LLC
訊號詞
Danger
危險分類
Aquatic Chronic 2 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Pyr. Liq. 1 - Repr. 2 - Skin Corr. 1B - STOT SE 3 - Water-react 1
標靶器官
Central nervous system
安全危害
儲存類別代碼
4.2 - Pyrophoric and self-heating hazardous materials
水污染物質分類(WGK)
WGK 3
閃點(°F)
-14.8 °F - closed cup
閃點(°C)
-26 °C - closed cup
Journal of the American Chemical Society, 111, 2981-2981 (1989)
ACS nano, 9(7), 7383-7391 (2015-07-01)
Two-dimensional (2D) semiconducting monolayer transition metal dichalcogenides (TMDCs) have stimulated lots of interest because they are direct bandgap materials that have reasonably good mobility values. However, contact between most metals and semiconducting TMDCs like 2H phase WSe2 are highly resistive
Organic letters, 11(20), 4596-4599 (2009-10-09)
A procedure for the coupling of aliphatic imines with allylic and allenic alkoxides is described. The success of these studies was enabled by a unique reactivity profile of Ti(IV) isopropoxide/n-BuLi compared to well-known Ti(IV) isopropoxide/RMgX systems.
Carbohydrate research, 141(1), 41-47 (1985-08-15)
Treatment of dimethyl sulfoxide with butyllithium leads to rapid formation of lithium methylsulfinyl carbanion. The reaction products tend to be significantly freer from impurities when lithium methylsulfinyl carbanion is used rather than sodium or potassium methylsulfinyl carbanion. This reagent gives
The Journal of organic chemistry, 68(16), 6387-6391 (2003-08-05)
The effects of lithium dialkylamide structure, mixed aggregate formation, and solvation on the stereoselectivity of ketone enolization were examined. Of the lithium dialkylamides examined, lithium tetramethylpiperidide (LiTMP) in THF resulted in the best enolization selectivity. The stereoselectivity was further improved
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