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蒸汽密度
~3 (vs air)
品質等級
形狀
liquid
濃度
1.7 M in pentane
密度
0.652 g/mL at 25 °C
儲存溫度
2-8°C
SMILES 字串
[Li]C(C)(C)C
InChI
1S/C4H9.Li/c1-4(2)3;/h1-3H3;
InChI 密鑰
BKDLGMUIXWPYGD-UHFFFAOYSA-N
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一般說明
叔丁基锂溶液(tert-BuLi)是一种有机锂化合物,用作有机化学中的强碱。它可促进锂-卤素交换反应,还可用于碳氢化合物和胺的去质子化。
應用
叔丁基锂可用作合成以下成分的强碱:
- 烷基锂衍生物,通过卤素-锂交换反应形成碘代烷烃和二碘烷烃。
- 通过还原插层法从[(InMo3Se3)n]合成无机聚合物[(LiMo3Se3)n]
- 通过与肉桂酸的C-C双键反应得到肉桂酸的加合物(1,3-和1,4-加合物)。
法律資訊
Sure/Seal is a trademark of Sigma-Aldrich Co. LLC
訊號詞
Danger
危險分類
Aquatic Chronic 2 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Pyr. Liq. 1 - Skin Corr. 1B - STOT SE 3 - Water-react 1
標靶器官
Central nervous system
儲存類別代碼
4.2 - Pyrophoric and self-heating hazardous materials
水污染物質分類(WGK)
WGK 2
閃點(°F)
-56.2 °F - closed cup
閃點(°C)
-49 °C - closed cup
Clean and convenient procedure for converting primary alkyl iodides and. alpha.,. omega.-diiodoalkanes into the corresponding alkyllithium derivatives by treatment with tert-butyllithium
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