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Merck

186198

Sigma-Aldrich

-丁基锂 溶液

1.7 M in pentane

别名:

2-甲基-2-丙酸锂, t-BuLi

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About This Item

线性分子式:
(CH3)3CLi
CAS号:
分子量:
64.06
Beilstein:
3587204
MDL號碼:
分類程式碼代碼:
12352103
PubChem物質ID:
NACRES:
NA.22

蒸汽密度

~3 (vs air)

品質等級

形狀

liquid

濃度

1.7 M in pentane

密度

0.652 g/mL at 25 °C

儲存溫度

2-8°C

SMILES 字串

[Li]C(C)(C)C

InChI

1S/C4H9.Li/c1-4(2)3;/h1-3H3;

InChI 密鑰

BKDLGMUIXWPYGD-UHFFFAOYSA-N

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一般說明

丁基锂溶液(tert-BuLi)是一种有机锂化合物,用作有机化学中的强碱。它可促进锂-卤素交换反应,还可用于碳氢化合物和胺的去质子化。

應用

丁基锂可用作合成以下成分的强碱:
  • 烷基锂衍生物,通过卤素-锂交换反应形成碘代烷烃和二碘烷烃。
  • 通过还原插层法从[(InMo3Se3)n]合成无机聚合物[(LiMo3Se3)n]
  • 通过与肉桂酸的C-C双键反应得到肉桂酸的加合物(1,3-和1,4-加合物)。

包裝

建议将25 mL Sure/Seal 瓶作为一次性瓶使用。 反复穿刺可能导致产品性能下降。

法律資訊

Sure/Seal is a trademark of Sigma-Aldrich Co. LLC

訊號詞

Danger

危險分類

Aquatic Chronic 2 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Pyr. Liq. 1 - Skin Corr. 1B - STOT SE 3 - Water-react 1

標靶器官

Central nervous system

儲存類別代碼

4.2 - Pyrophoric and self-heating hazardous materials

水污染物質分類(WGK)

WGK 2

閃點(°F)

-56.2 °F - closed cup

閃點(°C)

-49 °C - closed cup


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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