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化驗
98%
形狀
powder
mp
269-271 °C (lit.)
SMILES 字串
CN1C(=O)C=C(O)c2ccccc12
InChI
1S/C10H9NO2/c1-11-8-5-3-2-4-7(8)9(12)6-10(11)13/h2-6,12H,1H3
InChI 密鑰
RTNPPPQVXREFKX-UHFFFAOYSA-N
應用
4-Hydroxy-1-methyl-2(1H)-quinolone was used as nucleophile in electrochemical oxidation of catechols and the reaction was studied by cyclic voltammetry and controlled-potential coulometry. It was used in ceric ammonium nitrate-mediated oxidative cycloaddition of 1,3-dicarbonyls to conjugated compounds to yield substituted dihydrofurans, dihydrofurocoumarins, dihydrofuroquinolinones and dihydrofurophenalenones. It was used in the synthesis of :
- 3-(4-methoxybenzyl)-4-hydroxy-1-methylquinolinone
- 3-(benzo[d][1,3]dioxol-5-ylmethyl)-4-hydroxy-1-methylquinolin-2(1H)-one
- 3-(4-chlorobenzyl)-4-hydroxy-1-methylquinolin-2(1H)-one
- 3,3′-bis(4-chlorobenzylidene)-1,10-methylquinolin-2,20-(1H)-one
訊號詞
Warning
危險聲明
危險分類
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
標靶器官
Respiratory system
儲存類別代碼
11 - Combustible Solids
水污染物質分類（WGK）
WGK 3
閃點（°F）
Not applicable
閃點（°C）
Not applicable
個人防護裝備
dust mask type N95 (US), Eyeshields, Gloves
Mechanistic study of electrochemical oxidation of catechols in the presence of 4-hydroxy-1-methyl-2 (1H)-quinolone: Application to the electrochemical synthesis.
Fakhari AR, et al.
Electrochimica Acta, 50(27), 5322-5328 (2005)
Ceric ammonium nitrate (CAN)-mediated oxidative cycloaddition of 1, 3-dicarbonyls to conjugated compounds. Efficient synthesis of dihydrofurans, dihydrofurocoumarins, dihydrofuroquinolinones, dihydrofurophenalenones, and furonaphthoquinone natural products.
Lee YR, et al.
Tetrahedron, 56(45), 8845-8853 (2000)
Iridium catalysed alkylation of 4-hydroxy coumarin, 4-hydroxy-2-quinolones and quinolin-4 (1H)-one with alcohols under solvent free thermal conditions.
Grigg R, et al.
Tetrahedron, 65(36), 7468-7473 (2009)
Michael B Hicks et al.
The Analyst, 142(3), 525-536 (2017-01-18)
The use of a coulometric array detector in tandem with HPLC-UV was evaluated for the absolute quantitation of pharmaceutical compounds without standards, an important capability gap in contemporary pharmaceutical research and development. The high-efficiency LC flow-through electrochemical detector system allows
Mohankumar Saraladevi Resmi et al.
FEBS letters, 589(3), 332-341 (2015-01-06)
Type III polyketide synthases (PKSs) catalyze the biosynthesis of various medicinally important secondary metabolites in plants, but their role in growth and stress response is unclear. Here, we overexpressed quinolone synthase (QNS) from bael in tobacco. QNS-overexpressing plants showed an
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