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品質等級
化驗
98%
形狀
powder
反應適用性
reagent type: catalyst
reagent type: oxidant
reaction type: C-H Activation
mp
161-163 °C (lit.)
SMILES 字串
CC(OI(OC(C)=O)C1=CC=CC=C1)=O
InChI
1S/C10H11IO4/c1-8(12)14-11(15-9(2)13)10-6-4-3-5-7-10/h3-7H,1-2H3
InChI 密鑰
ZBIKORITPGTTGI-UHFFFAOYSA-N
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應用
橙花醇转化为橙花醛的 TEMPO 氧化反应中的化学计量氧化剂。用作铑催化的烯烃与氨基磺酸酯进行氮杂环丙化反应中的氧化剂。
用于合成各种杂环化合物的试剂。
用于室温下钯催化的吲哚的 2-芳基化反应。
肟和吡啶底物的未活化sp3 C-H键与PhI(OAc)2作为化学计量氧化剂进行高度区域选择性和化学选择性Pd(II)催化氧化。
儲存類別代碼
11 - Combustible Solids
水污染物質分類（WGK）
WGK 3
閃點（°F）
Not applicable
閃點（°C）
Not applicable
個人防護裝備
Eyeshields, Gloves, type N95 (US)
从最新的版本中选择一种：
分析证书(COA)
Lot/Batch Number
其他客户在看
Bikash Dangi et al.
Chembiochem : a European journal of chemical biology, 19(21), 2273-2282 (2018-08-24)
CYP154C8 catalyzes the hydroxylation of diverse steroids, as has previously been demonstrated, by using an NADH-dependent system including putidaredoxin and putidaredoxin reductase as redox partner proteins carrying electrons from NADH. In other reactions, CYP154C8 reconstituted with spinach ferredoxin and NADPH-dependent
Renhua Fan et al.
Organic & biomolecular chemistry, 6(24), 4615-4621 (2008-11-29)
An efficient one-pot oxidative decarboxylation-Friedel-Crafts reaction of acyclic alpha-amino acid derivatives with electron-rich aromatic compounds is reported. The reaction is activated by the combination of iodobenzene diacetate, iodine and iron dust, resulting in a mild and simple reaction system. The
S Garadnay et al.
Current medicinal chemistry, 8(6), 621-626 (2001-04-03)
The reactions of morphine and its derivatives with phenyliodo(III)diacetate (PIDA) have been studied. This methodology has not been introduced to morphine alkaloids, despite the fact that such a strategy would ensure dearomatization of the electrophilic aromatic ring of morphine derivatives
Hongzhang Han et al.
Macromolecular rapid communications, 40(10), e1900073-e1900073 (2019-04-04)
A hypervalent (HV) iodine(III)-containing crosslinker, (diacryloyloxyiodo)benzene, is synthesized and its crystal structure is reported. Highly branched polymers with hypervalent iodine(III) groups as the building blocks present at the branching points are synthesized by copolymerization of tert-butyl acrylate and the diacrylate
Tetrahedron, 62, 11331-11331 (2006)
商品
New! Rh2(esp)2, and exceptionally efficient and selective catalyst for C-H amination.
New! Rh2(esp)2, and exceptionally efficient and selective catalyst for C-H amination.
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