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1-[4-(3,5-Difluoro-benz-yloxy)-2-hy-droxy-phen-yl]ethanone.

Acta crystallographica. Section E, Structure reports online (2010-01-01)
Ya-Tuan Ma, An-Ling Zhang, Mao-Sen Yuan, Jin-Ming Gao
ABSTRACT

The title compound, C(15)H(12)F(2)O(3), has been obtained by the reaction of 2,4-dihy-droxy-lacetonephenone, potassium carbonate and 3,5-difluoro-benzyl bromide. The hy-droxy group is involved in an intra-molecular O-H⋯O hydrogen bond in each of the two independent mol-ecules in the asymmetric unit. The dihedral angle between the aromatic rings is 0.5 (2)° in one molecule and 1.9 (2)° in the other. In the crystal, weak C-H⋯O inter-actions link the mol-ecules into tetra-meric units aligned perpendicular to b.

MATERIALS
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Product Description

Sigma-Aldrich
3,5-Difluorobenzyl bromide, 98%