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Stabilization of zwitterionic aryltrifluoroborates against hydrolysis.

Chemical communications (Cambridge, England) (2010-08-07)
Casey R Wade, Haiyan Zhao, François P Gabbaï
PMID20689883
ABSTRACT

The presence of a proximal cationic group in zwitterionic aryltrifluoroborates such as o-(Ph(2)MeP)C(6)H(4)(BF(3)) stabilizes these compounds against hydrolysis.

MATERIALS
Product Number
Brand
Product Description
463086
Sigma-Aldrich
Boron trifluoride, electronic grade, ≥99.99%
83253
Supelco
Boron trifluoride - 1-butanol solution, ~10% in 1-butanol (∼1.3 M), for GC derivatization, LiChropur™