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31650

Sigma-Aldrich

Zinc chloride

puriss. p.a., ACS reagent, reag. ISO, reag. Ph. Eur., ≥98%

Synonym(s):

Dichlorozinc

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About This Item

Linear Formula:
ZnCl2
CAS Number:
7646-85-7
Molecular Weight:
136.30
EC Number:
231-592-0
MDL number:
MFCD00011295
UNSPSC Code:
12352302
PubChem Substance ID:
329753865
NACRES:
NA.21

grade

ACS reagent
puriss. p.a.

Quality Level

200

agency

USP/NF
reag. ISO
reag. Ph. Eur.

vapor pressure

1 mmHg ( 428 °C)

assay

≥98%

form

crystalline powder

impurities

≤0.002% total nitrogen (N)
≤0.005% insoluble in HCl
≤1.2% oxide chloride (as ZnO)

pH

4.6-5.5 (20 °C, 10%)

mp

293 °C (lit.)

anion traces

sulfate (SO42-): ≤20 mg/kg

cation traces

Ca: ≤10 mg/kg
Cd: ≤5 mg/kg
Cu: ≤10 mg/kg
Fe: ≤5 mg/kg
K: ≤0.02%
Mg: ≤10 mg/kg
Na: ≤0.05%
Pb: ≤10 mg/kg

SMILES string

[Cl-].[Cl-].[Zn++]

InChI

1S/2ClH.Zn/h2*1H;/q;;+2/p-2

InChI key

JIAARYAFYJHUJI-UHFFFAOYSA-L

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General description

Zinc chloride in combination with 1-ethyl-3-methylimidazolium chloride comprises a molten salt, which is employed in the electrodeposition studies of zinc.

Application

Zinc Chloride may be employed as a catalyst in Knoevenagel condensation of carbonyl compounds with active methylene group containing reagents. It may be used in the preparation of porous carbon nanofibers, useful in the fabrication of efficient electrodes for supercapacitors. It may be used as a catalyst in the preparation of poly(propylene fumarate).

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Danger

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Corr. 1B - STOT SE 3

target_organs

Respiratory system

Storage Class

8B - Non-combustible corrosive hazardous materials

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Self-Sustained Thin Webs Consisting of Porous Carbon Nanofibers for Supercapacitors via the Electrospinning of Polyacrylonitrile Solutions Containing Zinc
Kim C, et al.
Advanced Mat., 19(17), 2341-2346 (2007)
Electrodeposition of zinc from a Lewis acidic zinc chloride-1-ethyl-3-methylimidazolium chloride molten salt.
Lin Y-F and Sun I.
Electrochimica Acta, 44(16), 2771-2777 (1999)
Zinc chloride as a new catalyst for Knoevenagel condensation.
Shanthan RP and Venkataratnam RV.
Tetrahedron Letters, 32(41), 5821-5822 (1991)
Albert K Shung et al.
Journal of biomaterials science. Polymer edition, 13(1), 95-108 (2002-05-11)
Diethyl fumarate and propylene glycol were reacted in the presence of a zinc chloride catalyst to synthesize poly(propylene fumarate) (PPF) over a period of 12 hours. The kinetics of the transesterification polymerization at 130 degrees C, 150 degrees C, and
L Davies et al.
Cell death & disease, 2, e136-e136 (2011-04-01)
The activation and regulation of target genes by the tumour-suppressor p53 dictates the fate of a cell, with cell cycle arrest or apoptosis being two distinct outcomes. PERP (p53 apoptosis effector related to PMP-22), a p53 transcriptional target, is induced
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