74011

(±)-Diclofop

certified reference material, TraceCERT^®, Manufactured by: Sigma-Aldrich Production GmbH, Switzerland

• Synonym(s): (RS)-2-[4-(2,4-Dichlorophenoxy)phenoxy]propionic acid
• Empirical Formula (Hill Notation): C₁₅H₁₂Cl₂O₄
• CAS Number: 40843-25-2
• Molecular Weight: 327.16
• Beilstein/REAXYS Number: 2338390
• MDL number: MFCD00152216
• UNSPSC Code: 41116107
• NACRES: NA.24

Properties

• grade: certified reference material; TraceCERT^®
• Quality Level: 300
• product line: TraceCERT^®
• shelf life: limited shelf life, expiry date on the label
• manufacturer/tradename: Manufactured by: Sigma-Aldrich Production GmbH, Switzerland
• format: neat
• storage temp.: 2-8°C
• SMILES string: CC(Oc1ccc(Oc2ccc(Cl)cc2Cl)cc1)C(O)=O
• InChI: 1S/C15H12Cl2O4/c1-9(15(18)19)20-11-3-5-12(6-4-11)21-14-7-2-10(16)8-13(14)17/h2-9H,1H3,(H,18,19)
• InChI key: OOLBCHYXZDXLDS-UHFFFAOYSA-N

Description

General description

This certified reference material (CRM) is produced and certified in accordance with ISO/IEC 17025 and ISO 17034. The CRM is traceable to primary material from an NMI, e.g. NIST or NMIJ.
Certified content by quantitative NMR incl. uncertainty and expiry date are given on the certificate.
Download your certificate at: http://www.sigma-aldrich.com
(+/–)-Diclofop is a chiral herbicide that belongs to the chemical class of chiral aryloxyphenoxypropionate compounds. The actual herbicidal active ingredient― carboxylic acid, is released after application through hydrolysis of the ester. It is absorbed mainly through leaves and inhibits the biosynthesis of fatty acids by suppressing the activity of acetyl CoA carboxylase (ACCase). It is used for the post-emergence control of wild oats, wild millets, and other annual grass weeds commonly occurring in wheat, barley, rye, red fescue, and broad-leaved crops.
It was included on 1st June 2011 in Annex I of Directive 91/414/EEC by the European Commission Directive 2011/45/EU. It is authorized for use under EC Regulation No 1107/2009, as per the Commission Implementing Regulation (EU) No 540/2011, however it is a candidate for substitution.

Application

It is intended to be used as a certified reference material (CRM) for calibration in chromatography and other analytical techniques.
The (+/–)-Diclofop CRM can also be used as following:

• To evaluate the likely enantioselective oxidative stress produced in Microcystis aeruginosa by diclofop acid
• For analyzing the phytotoxic effects of diclofop acid enantiomers on the plant Arabidopsis thaliana
• To study the enantioselective toxicity of diclofop acid on the non-target rice Xiushui 63 seedlings
• In the chiral separation of diclofop-acid using one- and two- dimensional HPLC methods
• To determine the enantioselective toxicity and degradation of diclofop in three algal cultures

Recommended products

Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.

Legal Information

TraceCERT is a registered trademark of Merck KGaA, Darmstadt, Germany

Safety Information

• pictograms: GHS07
• signalword: Warning
• hcodes: H302
• pcodes: P264 - P270 - P301 + P312 - P501
• Hazard Classifications: Acute Tox. 4 Oral
• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable