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Potassium tetrakis(4-chlorophenyl)borate

Selectophore™, ≥98.0%

Synonym(s):

Tetrakis(4-chlorophenyl)boron potassium

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About This Item

Linear Formula:
(ClC6H4)4BK
CAS Number:
14680-77-4
Molecular Weight:
496.11
Beilstein/REAXYS Number:
4117827
EC Number:
238-723-0
MDL number:
MFCD00043105
UNSPSC Code:
26111700
PubChem Substance ID:
329759093

grade

for ion-selective electrodes

Quality Level

200

product line

Selectophore™

assay

≥98.0% (AT)
≥98.0%

form

solid

SMILES string

[K+].Clc1ccc(cc1)[B-](c2ccc(Cl)cc2)(c3ccc(Cl)cc3)c4ccc(Cl)cc4

InChI

1S/C24H16BCl4.K/c26-21-9-1-17(2-10-21)25(18-3-11-22(27)12-4-18,19-5-13-23(28)14-6-19)20-7-15-24(29)16-8-20;/h1-16H;/q-1;+1

InChI key

SAGICZRAKJSWLD-UHFFFAOYSA-N

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General description

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Application

Potassium tetrakis(4-chlorophenyl)borate was used as lipophilic anionic site in constructing fluorescent optode for sodium. It was also used as coating for the piezoelectric crystal in quantifying Potassium using quartz crystal microbalance.

Packaging

Bottomless glass bottle. Contents are inside inserted fused cone.

Legal Information

Selectophore is a trademark of Merck KGaA, Darmstadt, Germany

pictograms

Skull and crossbones
GHS06

signalword

Danger

hcodes

H301

Hazard Classifications

Acute Tox. 3 Oral

Storage Class

6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
BCCF8665
BCCC7856
BCCB7255
BCBW8211
BCBT2398

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Larisa Lvova et al.
Sensors (Basel, Switzerland), 13(5), 5841-5856 (2013-05-09)
5,10,15,20-Tetraferrocenyl porphyrin, H2TFcP, a simple example of a donor-acceptor system, was tested as ligand for the development of a novel multi-transduction chemical sensors aimed at the determination of transition metal ions. The fluorescence energy transfer between ferrocene donor and porphyrin
B D Pendley et al.
Analytical chemistry, 73(19), 4599-4606 (2001-10-19)
A new chronoamperometric method is used to estimate changes in the membrane composition of mobile-site, ionophore-based membranes. The characteristic features of the chronoamperometric curves (initial current, slope, break time) of valinomycin-based, potassium-selective membranes loaded with potassium tetrakis(4-chlorophenyl)borate are correlated with
Qianyu Zhang et al.
Sensors (Basel, Switzerland), 13(6), 6936-6945 (2013-05-28)
A flow biosensor for the detection of toxicity in water using the ammonia-oxidizing bacterium (AOB) Nitrosomonas europaea as a bioreceptor and a polymeric membrane ammonium-selective electrode as a transducer is described. The system is based on the inhibition effects of
Mihaela Dana Tutulea-Anastasiu et al.
Sensors (Basel, Switzerland), 13(4), 4367-4377 (2013-04-04)
All-solid-state sensors with polyvinyl chloride (PVC)-based membranes using off-the-shelf N-hydroxysuccinimide (NHS) and succinimide (Succ) ionophores were prepared using DOP (dioctyl phthalate) and NPOE (ortho-nitrophenyloctyl ether) as plasticizers. Good responses were obtained when NHS was used. The potentiometric response of the
Larisa Lvova et al.
Sensors (Basel, Switzerland), 21(4) (2021-03-07)
The metalloporphyrin ligand bearing incorporated anion-exchanger fragment, 5-[4-(3-trimethylammonium)propyloxyphenyl]-10,15,20-triphenylporphyrinate of Co(II) chloride, CoTPP-N, has been tested as anion-selective ionophore in PVC-based solvent polymeric membrane sensors. A plausible sensor working mechanism includes the axial coordination of the target anion on ionophore metal
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