8.20544

1-Dodecanethiol

for synthesis

• Synonym(s): 1-Dodecanethiol, Lauryl mercaptan, Dodecyl mercaptan
• Linear Formula: CH₃(CH₂)₁₁SH
• CAS Number: 112-55-0
• Molecular Weight: 202.40
• MDL number: MFCD00004885
• UNSPSC Code: 12352105
• EC Index Number: 203-984-1
• NACRES: NA.22

Properties

• vapor pressure: 0.002 hPa ( 20 °C)
• Quality Level: 200
• assay: ≥98.0% (GC)
• form: liquid
• autoignition temp.: 230 °C
• potency: >2000 mg/kg LD₅₀, oral (Rat)
• mp: -9--7 °C
• transition temp: flash point 127 °C
• density: 0.845 g/cm³ at 20 °C
• storage temp.: 2-30°C
• InChI: 1S/C12H26S/c1-2-3-4-5-6-7-8-9-10-11-12-13/h13H,2-12H2,1H3
• InChI key: WNAHIZMDSQCWRP-UHFFFAOYSA-N

Description

General description

1-Dodecanethiol is an alkyl thiol that can be used as an organic source of sulfur. It is used in the production of synthetic rubber, nonionic detergent, plastics, and pharmaceuticals.

Application

1-Dodecanethiol (1-DDT) can be used as:      

• A sulfur source and capping ligand in the synthesis of copper sulfide nanoparticles (Cu₂S) which can be applied as electron donor and hole acceptor in photocatalytic reactions.      
• A coordinating ligand to prepare Cu₂ZnSnS₄ (CZTS) nanocrystals to control the nucleation and growth of CZTS nanocrystals.

Zinc-doped copper indium sulfide (ZnCuInS₂) quantum dots can be functionalized with 1-decanethiol as a ligand to improve the charge mobility and luminance of organic light emitting diodes (OLEDs).

Analysis Note

Assay (GC, area%): ≥ 98.0 % (a/a)
Density (d 20 °C/ 4 °C): 0.844 - 0.846
Identity (IR): passes test

Safety Information

• pictograms: GHS05,GHS07,GHS09
• signalword: Danger
• hcodes: H314 - H317 - H410
• pcodes: P261 - P272 - P273 - P280 - P303 + P361 + P353 - P305 + P351 + P338
• Hazard Classifications: Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Corr. 1C - Skin Sens. 1A
• Storage Class: 8A - Combustible, corrosive hazardous materials
• wgk_germany: WGK 3
• flash_point_f: 262.4 °F - closed cup
• flash_point_c: 128 °C - closed cup