1.02521

Sodium hexanitrocobaltate(III)

[sodium cobalt(III)nitrite] for analysis EMSURE^® ACS,Reag. Ph Eur

• Synonym(s): Sodium hexanitrocobaltate(III), Cobalt(III) sodium nitrite, Sodium cobaltinitrite
• Linear Formula: Na₃[Co(NO₂)₆]
• CAS Number: 13600-98-1
• Molecular Weight: 403.94
• MDL number: MFCD00003512
• UNSPSC Code: 12352302
• EC Index Number: 237-077-7
• NACRES: NA.21

Properties

• grade: ACS reagent
• Quality Level: 300
• agency: reag. Ph. Eur.
• product line: EMSURE^®
• form: powder
• impurities: ≤0.02% Insoluble matter
• pH: 5 (20 °C, 100 g/L in H₂O)
• mp: 220 °C
• bulk density: 480 kg/m³
• anion traces: chloride (Cl^-): ≤0.005%
• cation traces: Fe: ≤0.002%
• storage temp.: 2-30°C
• InChI: 1S/Co.6HNO2.3Na/c;6*2-1-3;;;/h;6*(H,2,3);;;/q;;;;;;;3*+1/p-6
• InChI key: MUTOTFDDGIZNIK-UHFFFAOYSA-H

Description

Application

• One-pot synthesis of graphene-cobalt hydroxide composite nanosheets (Co/G NSs) for electrocatalytic water oxidation.: This article presents a study on the use of sodium hexanitrocobaltate(III) in a one-pot synthesis method for producing graphene-cobalt hydroxide composite nanosheets. These composites show significant potential for applications in electrocatalytic water oxidation, highlighting their importance in energy conversion and storage technologies (Mehmood R et al., 2018).


• Nitrosation with Sodium Hexanitrocobaltate(III).: This research discusses the use of sodium hexanitrocobaltate(III) as a reagent for the nitrosation process. It provides valuable insights into the application of this compound in organic synthesis, demonstrating its effectiveness in introducing nitroso groups into organic molecules, which is critical for the development of pharmaceuticals and agrochemicals (Stefane B et al., 1997).

Analysis Note

Identity: passes test
Insoluble matter: ≤ 0.02 %
Chloride (Cl): ≤ 0.005 %
Fe (Iron): ≤ 0.002 %
Suitability for Potassium determination: passes test

Legal Information

EMSURE is a registered trademark of Merck KGaA, Darmstadt, Germany

Safety Information

• pictograms: GHS03,GHS07,GHS08
• signalword: Danger
• hcodes: H272 - H315 - H317 - H319 - H334 - H335 - H351
• pcodes: P202 - P210 - P280 - P302 + P352 - P305 + P351 + P338 - P308 + P313
• Hazard Classifications: Carc. 2 - Eye Irrit. 2 - Ox. Sol. 2 - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3
• target_organs: Respiratory system
• Storage Class: 5.1B - Oxidizing hazardous materials
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable